Exceptional superionic conductivity in disordered sodium decahydro-closo-decaborate

Terrence J. Udovic; Motoaki Matsuo; Wan Si Tang; Hui Wu; Vitalie Stavila; Alexei V. Soloninin; Roman V. Skoryunov; Olga A. Babanova; Alexander V. Skripov; John J. Rush; Atsushi Unemoto; Hitoshi Takamura; Shin Ichi Orimo

doi:10.1002/adma.201403157

Exceptional superionic conductivity in disordered sodium decahydro-closo-decaborate

Terrence J. Udovic, Motoaki Matsuo, Wan Si Tang, Hui Wu, Vitalie Stavila, Alexei V. Soloninin, Roman V. Skoryunov, Olga A. Babanova, Alexander V. Skripov, John J. Rush, Atsushi Unemoto, Hitoshi Takamura, Shin Ichi Orimo

Research output: Contribution to journal › Article › peer-review

192 Citations (Scopus)

Abstract

Na₂B₁₀H₁₀ exhibits exceptional superionic conductivity above ca. 360 K (e.g., ca. 0.01 S cm^-1 at 383 K) concomitant with its transition from an ordered monoclinic structure to a face-centeredcubic arrangement of orientationally disordered B₁₀H₁₀^2- anions harboring a vacancy-rich Na⁺ cation sublattice. This discovery represents a major advancement for solid-state Na⁺ fast-ion conduction at technologically relevant device temperatures. (Graph Presented).

Original language	English
Pages (from-to)	7622-7626
Number of pages	5
Journal	Advanced Materials
Volume	26
Issue number	45
DOIs	https://doi.org/10.1002/adma.201403157
Publication status	Published - 2014 Dec

Keywords

Conductivity
Sodium conductors
Sodium decahydro-closo-decaborate
Solid-state electrolytes
Superionic

ASJC Scopus subject areas

Materials Science(all)
Mechanics of Materials
Mechanical Engineering

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10.1002/adma.201403157

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title = "Exceptional superionic conductivity in disordered sodium decahydro-closo-decaborate",

abstract = "Na2B10H10 exhibits exceptional superionic conductivity above ca. 360 K (e.g., ca. 0.01 S cm-1 at 383 K) concomitant with its transition from an ordered monoclinic structure to a face-centeredcubic arrangement of orientationally disordered B10H102- anions harboring a vacancy-rich Na+ cation sublattice. This discovery represents a major advancement for solid-state Na+ fast-ion conduction at technologically relevant device temperatures. (Graph Presented).",

keywords = "Conductivity, Sodium conductors, Sodium decahydro-closo-decaborate, Solid-state electrolytes, Superionic",

author = "Udovic, {Terrence J.} and Motoaki Matsuo and Tang, {Wan Si} and Hui Wu and Vitalie Stavila and Soloninin, {Alexei V.} and Skoryunov, {Roman V.} and Babanova, {Olga A.} and Skripov, {Alexander V.} and Rush, {John J.} and Atsushi Unemoto and Hitoshi Takamura and Orimo, {Shin Ichi}",

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doi = "10.1002/adma.201403157",

language = "English",

volume = "26",

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journal = "Advanced Materials",

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TY - JOUR

T1 - Exceptional superionic conductivity in disordered sodium decahydro-closo-decaborate

AU - Udovic, Terrence J.

AU - Matsuo, Motoaki

AU - Tang, Wan Si

AU - Wu, Hui

AU - Stavila, Vitalie

AU - Soloninin, Alexei V.

AU - Skoryunov, Roman V.

AU - Babanova, Olga A.

AU - Skripov, Alexander V.

AU - Rush, John J.

AU - Unemoto, Atsushi

AU - Takamura, Hitoshi

AU - Orimo, Shin Ichi

PY - 2014/12

Y1 - 2014/12

N2 - Na2B10H10 exhibits exceptional superionic conductivity above ca. 360 K (e.g., ca. 0.01 S cm-1 at 383 K) concomitant with its transition from an ordered monoclinic structure to a face-centeredcubic arrangement of orientationally disordered B10H102- anions harboring a vacancy-rich Na+ cation sublattice. This discovery represents a major advancement for solid-state Na+ fast-ion conduction at technologically relevant device temperatures. (Graph Presented).

AB - Na2B10H10 exhibits exceptional superionic conductivity above ca. 360 K (e.g., ca. 0.01 S cm-1 at 383 K) concomitant with its transition from an ordered monoclinic structure to a face-centeredcubic arrangement of orientationally disordered B10H102- anions harboring a vacancy-rich Na+ cation sublattice. This discovery represents a major advancement for solid-state Na+ fast-ion conduction at technologically relevant device temperatures. (Graph Presented).

KW - Conductivity

KW - Sodium conductors

KW - Sodium decahydro-closo-decaborate

KW - Solid-state electrolytes

KW - Superionic

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DO - 10.1002/adma.201403157

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JO - Advanced Materials

JF - Advanced Materials

SN - 0935-9648

IS - 45

ER -

Exceptional superionic conductivity in disordered sodium decahydro-closo-decaborate

Abstract

Keywords

ASJC Scopus subject areas

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