Evidence of asymmetric autocatalysis in the enantioselective addition of diisopropylzinc to pyrimidine-5-carbaldehyde using chiral pyrimidyl alkanol

Itaru Sato, Daisuke Omiya, Koichi Tsukiyama, Yoshihiro Ogi, Kenso Soai

Research output: Contribution to journalArticle

71 Citations (Scopus)

Abstract

Kinetic analysis of the relationship between the reaction time and the yields of the product in the enantioselective addition of diisopropylzinc to pyrimidine-5-carbaldehyde using chiral pyrimidyl alkanol proves that the reaction is autocatalytic.

Original languageEnglish
Pages (from-to)1965-1969
Number of pages5
JournalTetrahedron Asymmetry
Volume12
Issue number14
DOIs
Publication statusPublished - 2001 Aug 14

ASJC Scopus subject areas

  • Catalysis
  • Physical and Theoretical Chemistry
  • Organic Chemistry
  • Inorganic Chemistry

Fingerprint Dive into the research topics of 'Evidence of asymmetric autocatalysis in the enantioselective addition of diisopropylzinc to pyrimidine-5-carbaldehyde using chiral pyrimidyl alkanol'. Together they form a unique fingerprint.

  • Cite this