Abstract
The conformations of the chelate cycles in the X-ray structures of norbornadiene- and cyclooctadiene-rhodium complexes of (R,R)-1,2-bis[(o- methylphenyl)phenylphosphino]ethane are dramatically different. Nevertheless, they demonstrate the same sense of enantioselection in asymmetric hydrogenation of dehydroamino acids.
| Original language | English |
|---|---|
| Pages (from-to) | 2879-2882 |
| Number of pages | 4 |
| Journal | Tetrahedron Letters |
| Volume | 46 |
| Issue number | 16 |
| DOIs | |
| Publication status | Published - 2005 Apr 18 |
Keywords
- Asymmetric hydrogenation
- Chiral diphosphines
- Chiral rhodium complexes
- Sense of enantioselection
ASJC Scopus subject areas
- Biochemistry
- Drug Discovery
- Organic Chemistry
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Tsuruta, H., Imamoto, T., Yamaguchi, K., & Gridnev, I. D. (2005). Evidence for the importance of conformational equilibria in Rh-diphosphine complexes for the enantioselection in Rh-catalyzed asymmetric hydrogenation. Tetrahedron Letters, 46(16), 2879-2882. https://doi.org/10.1016/j.tetlet.2005.02.115