Evaluation of hyperpolarizability of nonlinear optical organic molecules by hyper-Rayleigh scattering

Takuo Kodaira; Akira Watanabe; Osamu Ito; Minoru Matsuda; Koen Clays; Andre Persoons

doi:10.1143/jjap.35.6074

Evaluation of hyperpolarizability of nonlinear optical organic molecules by hyper-Rayleigh scattering

Takuo Kodaira, Akira Watanabe, Osamu Ito, Minoru Matsuda, Koen Clays, Andre Persoons

Center for Mineral Processing and Metallurgy (CMPM)

Research output: Contribution to journal › Article › peer-review

4 Citations (Scopus)

Abstract

The hyperpolarizability β of nonlinear optical (NLO) organic molecules was determined by the hyper-Rayleigh scattering (HRS) technique. The β values obtained by using the HRS technique were compared with the values calculated using a semiempirical molecular orbital (MO) method, and good agreement between these values was obtained. The solvent dependence in the HRS measurements was also investigated for NLO organic molecules using p-dioxane and methanol. A specific interaction between the solute and solvent was concluded to influence the β value.

Original language	English
Pages (from-to)	6074-6078
Number of pages	5
Journal	Japanese Journal of Applied Physics, Part 1: Regular Papers and Short Notes and Review Papers
Volume	35
Issue number	12 A
DOIs	https://doi.org/10.1143/jjap.35.6074
Publication status	Published - 1996 Dec

Keywords

Electric-field-induced second harmonic generation
Hyper-Rayleigh scattering
Hyperpolarizability
Nonlinear optical organic molecule
Solvent dependance

ASJC Scopus subject areas

Engineering(all)
Physics and Astronomy(all)

Access to Document

10.1143/jjap.35.6074

Fingerprint Dive into the research topics of 'Evaluation of hyperpolarizability of nonlinear optical organic molecules by hyper-Rayleigh scattering'. Together they form a unique fingerprint.

Cite this

Evaluation of hyperpolarizability of nonlinear optical organic molecules by hyper-Rayleigh scattering. / Kodaira, Takuo; Watanabe, Akira; Ito, Osamu; Matsuda, Minoru; Clays, Koen; Persoons, Andre.

In: Japanese Journal of Applied Physics, Part 1: Regular Papers and Short Notes and Review Papers, Vol. 35, No. 12 A, 12.1996, p. 6074-6078.

Research output: Contribution to journal › Article › peer-review

@article{22682fe93b05440ca8f547d875b1e623,

title = "Evaluation of hyperpolarizability of nonlinear optical organic molecules by hyper-Rayleigh scattering",

abstract = "The hyperpolarizability β of nonlinear optical (NLO) organic molecules was determined by the hyper-Rayleigh scattering (HRS) technique. The β values obtained by using the HRS technique were compared with the values calculated using a semiempirical molecular orbital (MO) method, and good agreement between these values was obtained. The solvent dependence in the HRS measurements was also investigated for NLO organic molecules using p-dioxane and methanol. A specific interaction between the solute and solvent was concluded to influence the β value.",

keywords = "Electric-field-induced second harmonic generation, Hyper-Rayleigh scattering, Hyperpolarizability, Nonlinear optical organic molecule, Solvent dependance",

author = "Takuo Kodaira and Akira Watanabe and Osamu Ito and Minoru Matsuda and Koen Clays and Andre Persoons",

year = "1996",

month = dec,

doi = "10.1143/jjap.35.6074",

language = "English",

volume = "35",

pages = "6074--6078",

journal = "Japanese Journal of Applied Physics, Part 1: Regular Papers & Short Notes",

issn = "0021-4922",

publisher = "Japan Society of Applied Physics",

number = "12 A",

}

TY - JOUR

T1 - Evaluation of hyperpolarizability of nonlinear optical organic molecules by hyper-Rayleigh scattering

AU - Kodaira, Takuo

AU - Watanabe, Akira

AU - Ito, Osamu

AU - Matsuda, Minoru

AU - Clays, Koen

AU - Persoons, Andre

PY - 1996/12

Y1 - 1996/12

N2 - The hyperpolarizability β of nonlinear optical (NLO) organic molecules was determined by the hyper-Rayleigh scattering (HRS) technique. The β values obtained by using the HRS technique were compared with the values calculated using a semiempirical molecular orbital (MO) method, and good agreement between these values was obtained. The solvent dependence in the HRS measurements was also investigated for NLO organic molecules using p-dioxane and methanol. A specific interaction between the solute and solvent was concluded to influence the β value.

AB - The hyperpolarizability β of nonlinear optical (NLO) organic molecules was determined by the hyper-Rayleigh scattering (HRS) technique. The β values obtained by using the HRS technique were compared with the values calculated using a semiempirical molecular orbital (MO) method, and good agreement between these values was obtained. The solvent dependence in the HRS measurements was also investigated for NLO organic molecules using p-dioxane and methanol. A specific interaction between the solute and solvent was concluded to influence the β value.

KW - Electric-field-induced second harmonic generation

KW - Hyper-Rayleigh scattering

KW - Hyperpolarizability

KW - Nonlinear optical organic molecule

KW - Solvent dependance

UR - http://www.scopus.com/inward/record.url?scp=0030394733&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=0030394733&partnerID=8YFLogxK

U2 - 10.1143/jjap.35.6074

DO - 10.1143/jjap.35.6074

M3 - Article

AN - SCOPUS:0030394733

VL - 35

SP - 6074

EP - 6078

JO - Japanese Journal of Applied Physics, Part 1: Regular Papers & Short Notes

JF - Japanese Journal of Applied Physics, Part 1: Regular Papers & Short Notes

SN - 0021-4922

IS - 12 A

ER -

Evaluation of hyperpolarizability of nonlinear optical organic molecules by hyper-Rayleigh scattering

Abstract

Keywords

ASJC Scopus subject areas

Access to Document

Other files and links

Cite this