Eu fulleride formation studied by photoemission spectroscopy

H. Yoshikawa; S. Kuroshima; I. Hirosawa; K. Tanigaki; J. Mizuki

doi:10.1016/0009-2614(95)00445-A

Eu fulleride formation studied by photoemission spectroscopy

H. Yoshikawa, S. Kuroshima, I. Hirosawa, K. Tanigaki, J. Mizuki

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18 Citations (Scopus)

Abstract

A photoemission study of C₆₀ thin films evaporated on Eu clarifies that the t_1u derived states are occupied by electron transfer from Eu to C₆₀. This result suggests that Eu forms a C₆₀ fulleride whose electronic structure is close to the semiconducting phase like K₄C₆₀. It is also concluded that longer annealing breaks the intramolecular chemical bonds in the C₆₀ cage.

Original language	English
Pages (from-to)	103-106
Number of pages	4
Journal	Chemical Physics Letters
Volume	239
Issue number	1-3
DOIs	https://doi.org/10.1016/0009-2614(95)00445-A
Publication status	Published - 1995 Jun 9
Externally published	Yes

ASJC Scopus subject areas

Physics and Astronomy(all)
Physical and Theoretical Chemistry

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10.1016/0009-2614(95)00445-A

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title = "Eu fulleride formation studied by photoemission spectroscopy",

abstract = "A photoemission study of C60 thin films evaporated on Eu clarifies that the t1u derived states are occupied by electron transfer from Eu to C60. This result suggests that Eu forms a C60 fulleride whose electronic structure is close to the semiconducting phase like K4C60. It is also concluded that longer annealing breaks the intramolecular chemical bonds in the C60 cage.",

author = "H. Yoshikawa and S. Kuroshima and I. Hirosawa and K. Tanigaki and J. Mizuki",

year = "1995",

month = jun,

day = "9",

doi = "10.1016/0009-2614(95)00445-A",

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volume = "239",

pages = "103--106",

journal = "Chemical Physics Letters",

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T1 - Eu fulleride formation studied by photoemission spectroscopy

AU - Yoshikawa, H.

AU - Kuroshima, S.

AU - Hirosawa, I.

AU - Tanigaki, K.

AU - Mizuki, J.

PY - 1995/6/9

Y1 - 1995/6/9

N2 - A photoemission study of C60 thin films evaporated on Eu clarifies that the t1u derived states are occupied by electron transfer from Eu to C60. This result suggests that Eu forms a C60 fulleride whose electronic structure is close to the semiconducting phase like K4C60. It is also concluded that longer annealing breaks the intramolecular chemical bonds in the C60 cage.

AB - A photoemission study of C60 thin films evaporated on Eu clarifies that the t1u derived states are occupied by electron transfer from Eu to C60. This result suggests that Eu forms a C60 fulleride whose electronic structure is close to the semiconducting phase like K4C60. It is also concluded that longer annealing breaks the intramolecular chemical bonds in the C60 cage.

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JO - Chemical Physics Letters

JF - Chemical Physics Letters

SN - 0009-2614

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ER -

Eu fulleride formation studied by photoemission spectroscopy

Abstract

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