Ethyl-substituted stilbazolium derivatives for second-order nonlinear optics

Shuji Okada; Kyoko Nogi; Anwar; Kyoko Tsuji; Xuan Ming Duan; Hidetoshi Oikawa; Hiro Matsuda; Hachiro Nakanishi

doi:10.1143/jjap.42.668

Ethyl-substituted stilbazolium derivatives for second-order nonlinear optics

Shuji Okada, Kyoko Nogi, Anwar, Kyoko Tsuji, Xuan Ming Duan, Hidetoshi Oikawa, Hiro Matsuda, Hachiro Nakanishi

Research output: Contribution to journal › Article › peer-review

32 Citations (Scopus)

Abstract

1-Methyl-4-(2-(4-dimethylamino)phenyl)pyridinium iodide and its three analogues with ethyl-substituted cations were prepared. The solubility in organic solvents was confirmed to increase by ethyl substitution. Counter anion exchange afforded several SHG active crystals even in ethyl-substituted derivatives, and 1-ethyl-4-(2-(4-(dimethylamino)phenyl)ethenyl)pyridinium p-nitrobenzenesulfonate was estimated to have an off-diagonal d component twice as larger as that of 1-methyl-4-(2-(4-(dimethylamino)phenyl)ethenyl)pyridinium p-toluenesulfonate (DAST).

Original language	English
Pages (from-to)	668-671
Number of pages	4
Journal	Journal of Trauma and Acute Care Surgery
Volume	42
Issue number	2 A
DOIs	https://doi.org/10.1143/jjap.42.668
Publication status	Published - 2003 Feb
Externally published	Yes

Keywords

DAST
Organic ionic crystal
Second-order nonlinear optics
Solubility
Stilbazolium salt

ASJC Scopus subject areas

Surgery
Critical Care and Intensive Care Medicine

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10.1143/jjap.42.668

Cite this

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title = "Ethyl-substituted stilbazolium derivatives for second-order nonlinear optics",

abstract = "1-Methyl-4-(2-(4-dimethylamino)phenyl)pyridinium iodide and its three analogues with ethyl-substituted cations were prepared. The solubility in organic solvents was confirmed to increase by ethyl substitution. Counter anion exchange afforded several SHG active crystals even in ethyl-substituted derivatives, and 1-ethyl-4-(2-(4-(dimethylamino)phenyl)ethenyl)pyridinium p-nitrobenzenesulfonate was estimated to have an off-diagonal d component twice as larger as that of 1-methyl-4-(2-(4-(dimethylamino)phenyl)ethenyl)pyridinium p-toluenesulfonate (DAST).",

keywords = "DAST, Organic ionic crystal, Second-order nonlinear optics, Solubility, Stilbazolium salt",

author = "Shuji Okada and Kyoko Nogi and Anwar and Kyoko Tsuji and Duan, {Xuan Ming} and Hidetoshi Oikawa and Hiro Matsuda and Hachiro Nakanishi",

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language = "English",

volume = "42",

pages = "668--671",

journal = "Journal of Trauma and Acute Care Surgery",

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publisher = "Lippincott Williams and Wilkins",

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TY - JOUR

T1 - Ethyl-substituted stilbazolium derivatives for second-order nonlinear optics

AU - Okada, Shuji

AU - Nogi, Kyoko

AU - Anwar,

AU - Tsuji, Kyoko

AU - Duan, Xuan Ming

AU - Oikawa, Hidetoshi

AU - Matsuda, Hiro

AU - Nakanishi, Hachiro

PY - 2003/2

Y1 - 2003/2

N2 - 1-Methyl-4-(2-(4-dimethylamino)phenyl)pyridinium iodide and its three analogues with ethyl-substituted cations were prepared. The solubility in organic solvents was confirmed to increase by ethyl substitution. Counter anion exchange afforded several SHG active crystals even in ethyl-substituted derivatives, and 1-ethyl-4-(2-(4-(dimethylamino)phenyl)ethenyl)pyridinium p-nitrobenzenesulfonate was estimated to have an off-diagonal d component twice as larger as that of 1-methyl-4-(2-(4-(dimethylamino)phenyl)ethenyl)pyridinium p-toluenesulfonate (DAST).

AB - 1-Methyl-4-(2-(4-dimethylamino)phenyl)pyridinium iodide and its three analogues with ethyl-substituted cations were prepared. The solubility in organic solvents was confirmed to increase by ethyl substitution. Counter anion exchange afforded several SHG active crystals even in ethyl-substituted derivatives, and 1-ethyl-4-(2-(4-(dimethylamino)phenyl)ethenyl)pyridinium p-nitrobenzenesulfonate was estimated to have an off-diagonal d component twice as larger as that of 1-methyl-4-(2-(4-(dimethylamino)phenyl)ethenyl)pyridinium p-toluenesulfonate (DAST).

KW - DAST

KW - Organic ionic crystal

KW - Second-order nonlinear optics

KW - Solubility

KW - Stilbazolium salt

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DO - 10.1143/jjap.42.668

M3 - Article

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SN - 2163-0755

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EP - 671

JO - Journal of Trauma and Acute Care Surgery

JF - Journal of Trauma and Acute Care Surgery

IS - 2 A

ER -

Ethyl-substituted stilbazolium derivatives for second-order nonlinear optics

Abstract

Keywords

ASJC Scopus subject areas

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