ESR studies of halogen-bridged mixed-metal compounds Ni1-xPdx(chxn)2Br3

S. Kuroda; K. Marumoto; T. Manabe; M. Yamashita

doi:10.1016/S0379-6779(98)00670-5

ESR studies of halogen-bridged mixed-metal compounds Ni_1-xPd_x(chxn)₂Br₃

S. Kuroda, K. Marumoto, T. Manabe, M. Yamashita

Research output: Contribution to journal › Conference article › peer-review

9 Citations (Scopus)

Abstract

Quasi-one-dimensional halogen-bridged mixed-metal complexes, Ni_1-xPd_x(chxn)₂Br₃ have been studied by ESR. For all x-values, spin susceptibility χ showed Curie-like behavior at low temperatures, while weakly temperature dependent behavior for higher temperatures. The absolute values of χ at RT showed a clear enhancement from the linear summation of susceptibilities of Ni and Pd fractions. ESR linewidth showed monotomic decrease from Ni to Pd side. These magnetic behaviors are discussed in relation to the occurrence of novel electronic states associated with mixed-metal chains.

Original language	English
Pages (from-to)	2155-2156
Number of pages	2
Journal	Synthetic Metals
Volume	103
Issue number	1-3
DOIs	https://doi.org/10.1016/S0379-6779(98)00670-5
Publication status	Published - 1999 Jun 24
Externally published	Yes
Event	Proceedings of the 1998 International Conference on Science and Technology of Synthetic Metals (ICSM-98) - Montpellier Duration: 1998 Jul 12 → 1998 Jul 18

ASJC Scopus subject areas

Electronic, Optical and Magnetic Materials
Condensed Matter Physics
Mechanics of Materials
Mechanical Engineering
Metals and Alloys
Materials Chemistry

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10.1016/S0379-6779(98)00670-5

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title = "ESR studies of halogen-bridged mixed-metal compounds Ni1-xPdx(chxn)2Br3",

abstract = "Quasi-one-dimensional halogen-bridged mixed-metal complexes, Ni1-xPdx(chxn)2Br3 have been studied by ESR. For all x-values, spin susceptibility χ showed Curie-like behavior at low temperatures, while weakly temperature dependent behavior for higher temperatures. The absolute values of χ at RT showed a clear enhancement from the linear summation of susceptibilities of Ni and Pd fractions. ESR linewidth showed monotomic decrease from Ni to Pd side. These magnetic behaviors are discussed in relation to the occurrence of novel electronic states associated with mixed-metal chains.",

author = "S. Kuroda and K. Marumoto and T. Manabe and M. Yamashita",

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TY - JOUR

T1 - ESR studies of halogen-bridged mixed-metal compounds Ni1-xPdx(chxn)2Br3

AU - Kuroda, S.

AU - Marumoto, K.

AU - Manabe, T.

AU - Yamashita, M.

PY - 1999/6/24

Y1 - 1999/6/24

N2 - Quasi-one-dimensional halogen-bridged mixed-metal complexes, Ni1-xPdx(chxn)2Br3 have been studied by ESR. For all x-values, spin susceptibility χ showed Curie-like behavior at low temperatures, while weakly temperature dependent behavior for higher temperatures. The absolute values of χ at RT showed a clear enhancement from the linear summation of susceptibilities of Ni and Pd fractions. ESR linewidth showed monotomic decrease from Ni to Pd side. These magnetic behaviors are discussed in relation to the occurrence of novel electronic states associated with mixed-metal chains.

AB - Quasi-one-dimensional halogen-bridged mixed-metal complexes, Ni1-xPdx(chxn)2Br3 have been studied by ESR. For all x-values, spin susceptibility χ showed Curie-like behavior at low temperatures, while weakly temperature dependent behavior for higher temperatures. The absolute values of χ at RT showed a clear enhancement from the linear summation of susceptibilities of Ni and Pd fractions. ESR linewidth showed monotomic decrease from Ni to Pd side. These magnetic behaviors are discussed in relation to the occurrence of novel electronic states associated with mixed-metal chains.

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U2 - 10.1016/S0379-6779(98)00670-5

DO - 10.1016/S0379-6779(98)00670-5

M3 - Conference article

AN - SCOPUS:0033138157

VL - 103

SP - 2155

EP - 2156

JO - Synthetic Metals

JF - Synthetic Metals

SN - 0379-6779

IS - 1-3

T2 - Proceedings of the 1998 International Conference on Science and Technology of Synthetic Metals (ICSM-98)

Y2 - 12 July 1998 through 18 July 1998

ER -

ESR studies of halogen-bridged mixed-metal compounds Ni_1-xPd_x(chxn)₂Br₃

Abstract

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