Enzymatic resolution of (±)-2-exo-7-syn-7-(1-propynyl)norbornan-2- ol, a key synthetic intermediate for jasmonoids

Hiromasa Kiyota, Daisuke Nakashima, Shigefumi Kuwahara, Takayuki Oritani

Research output: Contribution to journalArticle

Abstract

Lipase-catalyzed resolution of 2-exo-7-syn-7-(1′-propynyl)norbornan- 2-ol, a key synthetic intermediate for jasmonoids, was achieved using vinyl chloroacetate as an acyl donor.

Original languageEnglish
Pages (from-to)1441-1442
Number of pages2
JournalZeitschrift fur Naturforschung - Section B Journal of Chemical Sciences
Volume63
Issue number12
Publication statusPublished - 2008 Dec 1

Keywords

  • Bicyclo[2.2.1 ]heptan-2-ol
  • Chloroacetate
  • Enzymatic resolution
  • Lipases
  • Transesterification

ASJC Scopus subject areas

  • Chemistry(all)

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