Energy Dependence of ‘Molecular Rocket Reaction’ in Modified Metallocene - Cyclodextrin Inclusion Compound and Comparison with Those in Other Systems

Hideaki Matsue, Iwao Yamaguchi, Tsutomu Sekine, Kenji Yoshihara

Research output: Contribution to journalArticle

1 Citation (Scopus)

Abstract

‘Molecular rocket reaction’ was confirmed in modified metallocene-/?-cyclodextrin (CD) inclusion compound for the first time. Energy dependence of the reaction was examined in the range between 100 eV and several tens keV. The curve revealed at least an order of 0.5% of rocket survival probability below 126 eV and a nearly constant value (-0.2%) above 130 eV. The energy dependence curve was discussed in relation to those in metal β-diketonates, phtalocyanines, metallocenes and normal metallocene-β-CD inclusion compounds.

Original languageEnglish
Pages (from-to)163-168
Number of pages6
JournalRadiochimica Acta
Volume68
Issue number3
DOIs
Publication statusPublished - 1995 Mar

Keywords

  • Inclusion compound
  • Metallocene
  • Modified MCp2-β-CD
  • Molecular rocket reaction
  • β-Cyclodextrin

ASJC Scopus subject areas

  • Physical and Theoretical Chemistry

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