Energy Dependence of ‘Molecular Rocket Reaction’ in Modified Metallocene - Cyclodextrin Inclusion Compound and Comparison with Those in Other Systems

Hideaki Matsue; Iwao Yamaguchi; Tsutomu Sekine; Kenji Yoshihara

doi:10.1524/ract.1995.68.3.163

Energy Dependence of ‘Molecular Rocket Reaction’ in Modified Metallocene - Cyclodextrin Inclusion Compound and Comparison with Those in Other Systems

Hideaki Matsue, Iwao Yamaguchi, Tsutomu Sekine, Kenji Yoshihara

Division of Developmental Research in Education Programs

Research output: Contribution to journal › Article › peer-review

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Abstract

‘Molecular rocket reaction’ was confirmed in modified metallocene-/?-cyclodextrin (CD) inclusion compound for the first time. Energy dependence of the reaction was examined in the range between 100 eV and several tens keV. The curve revealed at least an order of 0.5% of rocket survival probability below 126 eV and a nearly constant value (-0.2%) above 130 eV. The energy dependence curve was discussed in relation to those in metal β-diketonates, phtalocyanines, metallocenes and normal metallocene-β-CD inclusion compounds.

Original language	English
Pages (from-to)	163-168
Number of pages	6
Journal	Radiochimica Acta
Volume	68
Issue number	3
DOIs	https://doi.org/10.1524/ract.1995.68.3.163
Publication status	Published - 1995 Mar

Keywords

Inclusion compound
Metallocene
Modified MCp2-β-CD
Molecular rocket reaction
β-Cyclodextrin

ASJC Scopus subject areas

Physical and Theoretical Chemistry

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10.1524/ract.1995.68.3.163

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title = "Energy Dependence of {\textquoteleft}Molecular Rocket Reaction{\textquoteright} in Modified Metallocene - Cyclodextrin Inclusion Compound and Comparison with Those in Other Systems",

abstract = "{\textquoteleft}Molecular rocket reaction{\textquoteright} was confirmed in modified metallocene-/?-cyclodextrin (CD) inclusion compound for the first time. Energy dependence of the reaction was examined in the range between 100 eV and several tens keV. The curve revealed at least an order of 0.5% of rocket survival probability below 126 eV and a nearly constant value (-0.2%) above 130 eV. The energy dependence curve was discussed in relation to those in metal β-diketonates, phtalocyanines, metallocenes and normal metallocene-β-CD inclusion compounds.",

keywords = "Inclusion compound, Metallocene, Modified MCp2-β-CD, Molecular rocket reaction, β-Cyclodextrin",

author = "Hideaki Matsue and Iwao Yamaguchi and Tsutomu Sekine and Kenji Yoshihara",

note = "Funding Information: This work was partly supported by a grant from the Inamori Foundation.",

year = "1995",

month = mar,

doi = "10.1524/ract.1995.68.3.163",

language = "English",

volume = "68",

pages = "163--168",

journal = "Radiochimica Acta",

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publisher = "R. Oldenbourg",

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TY - JOUR

T1 - Energy Dependence of ‘Molecular Rocket Reaction’ in Modified Metallocene - Cyclodextrin Inclusion Compound and Comparison with Those in Other Systems

AU - Matsue, Hideaki

AU - Yamaguchi, Iwao

AU - Sekine, Tsutomu

AU - Yoshihara, Kenji

N1 - Funding Information: This work was partly supported by a grant from the Inamori Foundation.

PY - 1995/3

Y1 - 1995/3

N2 - ‘Molecular rocket reaction’ was confirmed in modified metallocene-/?-cyclodextrin (CD) inclusion compound for the first time. Energy dependence of the reaction was examined in the range between 100 eV and several tens keV. The curve revealed at least an order of 0.5% of rocket survival probability below 126 eV and a nearly constant value (-0.2%) above 130 eV. The energy dependence curve was discussed in relation to those in metal β-diketonates, phtalocyanines, metallocenes and normal metallocene-β-CD inclusion compounds.

AB - ‘Molecular rocket reaction’ was confirmed in modified metallocene-/?-cyclodextrin (CD) inclusion compound for the first time. Energy dependence of the reaction was examined in the range between 100 eV and several tens keV. The curve revealed at least an order of 0.5% of rocket survival probability below 126 eV and a nearly constant value (-0.2%) above 130 eV. The energy dependence curve was discussed in relation to those in metal β-diketonates, phtalocyanines, metallocenes and normal metallocene-β-CD inclusion compounds.

KW - Inclusion compound

KW - Metallocene

KW - Modified MCp2-β-CD

KW - Molecular rocket reaction

KW - β-Cyclodextrin

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DO - 10.1524/ract.1995.68.3.163

M3 - Article

AN - SCOPUS:0342410586

SN - 0033-8230

VL - 68

SP - 163

EP - 168

JO - Radiochimica Acta

JF - Radiochimica Acta

IS - 3

ER -

Energy Dependence of ‘Molecular Rocket Reaction’ in Modified Metallocene - Cyclodextrin Inclusion Compound and Comparison with Those in Other Systems

Abstract

Keywords

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