Abstract
Electron nuclear double resonance (ENDOR) spectroscopy of oxoiron(IV) porphyrin π-cation radical complexes with pyrrole β-substituted porphyrins is reported. Hyperfine coupling constants (A H) of the pyrrole β-mefhyl groups were determined. Comparison of the A H values with those of compound I of peroxidase and catalase indicated the a 1u porphyrin π-cation radical states of these compound I.
Original language | English |
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Pages (from-to) | 68-69 |
Number of pages | 2 |
Journal | Chemistry Letters |
Volume | 38 |
Issue number | 1 |
DOIs | |
Publication status | Published - 2009 Jul 20 |
ASJC Scopus subject areas
- Chemistry(all)