Enantioselective total synthesis of (+)-sarcodictyenone

Takako Yamazaki, Minoru Ishikawa, Miki Uemura, Yuko Kanda, Hisashi Takei, Morio Asaoka

Research output: Contribution to journalArticlepeer-review

2 Citations (Scopus)

Abstract

The first enantioselective total synthesis of (+)-sarcodictyenone is described [4.3% overall yield from (5R,6R)-6-methyl-5-trimethylsily-2-cyclohexenone]. This work establishes the absolute stereochemistry of the natural product.

Original languageEnglish
Pages (from-to)1895-1900
Number of pages6
JournalTetrahedron
Volume64
Issue number8
DOIs
Publication statusPublished - 2008 Feb 18
Externally publishedYes

Keywords

  • (+)-Sarcodictyenone
  • Asymmetric synthesis
  • Hydroxycyclohexenone
  • Terpenoid

ASJC Scopus subject areas

  • Biochemistry
  • Drug Discovery
  • Organic Chemistry

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