Enantioselective synthesis induced by chiral epoxides in conjunction with asymmetric autocatalysis

Tsuneomi Kawasaki; Masako Shimizu; Kenta Suzuki; Itaru Sato; Kenso Soai

doi:10.1016/j.tetasy.2004.09.036

Enantioselective synthesis induced by chiral epoxides in conjunction with asymmetric autocatalysis

Tsuneomi Kawasaki, Masako Shimizu, Kenta Suzuki, Itaru Sato, Kenso Soai

SCI - Research and Analytical Center for Giant Molecules

Research output: Contribution to journal › Article › peer-review

20 Citations (Scopus)

Abstract

5-Pyrimidyl alkanol with an enantiomeric excess of up to 96% was formed using chiral epoxides as a chiral initiator in the enantioselective addition of diisopropylzinc to pyrimidine-5-carbaldehyde, in conjunction with asymmetric autocatalysis.

Original language	English
Pages (from-to)	3699-3701
Number of pages	3
Journal	Tetrahedron Asymmetry
Volume	15
Issue number	23
DOIs	https://doi.org/10.1016/j.tetasy.2004.09.036
Publication status	Published - 2004 Nov 29

ASJC Scopus subject areas

Catalysis
Physical and Theoretical Chemistry
Organic Chemistry
Inorganic Chemistry

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title = "Enantioselective synthesis induced by chiral epoxides in conjunction with asymmetric autocatalysis",

abstract = "5-Pyrimidyl alkanol with an enantiomeric excess of up to 96% was formed using chiral epoxides as a chiral initiator in the enantioselective addition of diisopropylzinc to pyrimidine-5-carbaldehyde, in conjunction with asymmetric autocatalysis.",

author = "Tsuneomi Kawasaki and Masako Shimizu and Kenta Suzuki and Itaru Sato and Kenso Soai",

year = "2004",

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AU - Kawasaki, Tsuneomi

AU - Shimizu, Masako

AU - Suzuki, Kenta

AU - Sato, Itaru

AU - Soai, Kenso

PY - 2004/11/29

Y1 - 2004/11/29

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AB - 5-Pyrimidyl alkanol with an enantiomeric excess of up to 96% was formed using chiral epoxides as a chiral initiator in the enantioselective addition of diisopropylzinc to pyrimidine-5-carbaldehyde, in conjunction with asymmetric autocatalysis.

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DO - 10.1016/j.tetasy.2004.09.036

M3 - Article

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JO - Tetrahedron Asymmetry

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