Enantioselective hydrophosphinylation of 1-alkenylphosphine oxides catalyzed by chiral strong Brønsted base

Azusa Kondoh; Sho Ishikawa; Masahiro Terada

doi:10.1039/d0ob01778g

Enantioselective hydrophosphinylation of 1-alkenylphosphine oxides catalyzed by chiral strong Brønsted base

Azusa Kondoh, Sho Ishikawa, Masahiro Terada

Research output: Contribution to journal › Article › peer-review

Abstract

A catalytic enantioselective addition of diarylphosphine oxides to 1-alkenyl(diaryl)phosphine oxides was achieved by using a chiral ureate as a chiral strong Brønsted base catalyst. The reaction followed by the reduction of phosphine oxide moieties provided chiral 1,2-diphosphinoalkanes, which are a family of useful chiral ligands for asymmetric transition metal catalysis. This journal is

Original language	English
Pages (from-to)	7814-7817
Number of pages	4
Journal	Organic and Biomolecular Chemistry
Volume	18
Issue number	39
DOIs	https://doi.org/10.1039/d0ob01778g
Publication status	Published - 2020 Oct 21

ASJC Scopus subject areas

Biochemistry
Physical and Theoretical Chemistry
Organic Chemistry

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title = "Enantioselective hydrophosphinylation of 1-alkenylphosphine oxides catalyzed by chiral strong Br{\o}nsted base",

abstract = "A catalytic enantioselective addition of diarylphosphine oxides to 1-alkenyl(diaryl)phosphine oxides was achieved by using a chiral ureate as a chiral strong Br{\o}nsted base catalyst. The reaction followed by the reduction of phosphine oxide moieties provided chiral 1,2-diphosphinoalkanes, which are a family of useful chiral ligands for asymmetric transition metal catalysis. This journal is ",

author = "Azusa Kondoh and Sho Ishikawa and Masahiro Terada",

note = "Funding Information: This research was supported by a Grant-in-Aid for Scientific Research on Innovative Areas “Hybrid Catalysis for Enabling Molecular Synthesis on Demand” (JP17H06447) from MEXT (Japan) and a Grant-in-Aid for Scientific Research (S) (JP16H06354) from the JSPS. We thank JSPS for a research fellowship for Young Scientists (S. I.). Publisher Copyright: {\textcopyright} The Royal Society of Chemistry.",

year = "2020",

month = oct,

day = "21",

doi = "10.1039/d0ob01778g",

language = "English",

volume = "18",

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journal = "Organic and Biomolecular Chemistry",

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publisher = "Royal Society of Chemistry",

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T1 - Enantioselective hydrophosphinylation of 1-alkenylphosphine oxides catalyzed by chiral strong Brønsted base

AU - Kondoh, Azusa

AU - Ishikawa, Sho

AU - Terada, Masahiro

N1 - Funding Information: This research was supported by a Grant-in-Aid for Scientific Research on Innovative Areas “Hybrid Catalysis for Enabling Molecular Synthesis on Demand” (JP17H06447) from MEXT (Japan) and a Grant-in-Aid for Scientific Research (S) (JP16H06354) from the JSPS. We thank JSPS for a research fellowship for Young Scientists (S. I.). Publisher Copyright: © The Royal Society of Chemistry.

PY - 2020/10/21

Y1 - 2020/10/21

N2 - A catalytic enantioselective addition of diarylphosphine oxides to 1-alkenyl(diaryl)phosphine oxides was achieved by using a chiral ureate as a chiral strong Brønsted base catalyst. The reaction followed by the reduction of phosphine oxide moieties provided chiral 1,2-diphosphinoalkanes, which are a family of useful chiral ligands for asymmetric transition metal catalysis. This journal is

AB - A catalytic enantioselective addition of diarylphosphine oxides to 1-alkenyl(diaryl)phosphine oxides was achieved by using a chiral ureate as a chiral strong Brønsted base catalyst. The reaction followed by the reduction of phosphine oxide moieties provided chiral 1,2-diphosphinoalkanes, which are a family of useful chiral ligands for asymmetric transition metal catalysis. This journal is

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Enantioselective hydrophosphinylation of 1-alkenylphosphine oxides catalyzed by chiral strong Brønsted base

Abstract

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