Abstract
The [2,3] sigmatropic rearrangement of α-propargyloxyacetic acids was achieved by the use of BaLi-(-)-sparteine complex in toluene. BuLi-chiral ligand complexes are stronger bases than lithium amides, so they are expected to be good mediators of this reaction.
| Original language | English |
|---|---|
| Pages (from-to) | 335-336 |
| Number of pages | 2 |
| Journal | Chemical and Pharmaceutical Bulletin |
| Volume | 46 |
| Issue number | 2 |
| DOIs | |
| Publication status | Published - 1998 Feb |
| Externally published | Yes |
Keywords
- BuLi-(-)-sparteine complex
- Chiral allenylalcohol
- Enantioselective [2,3]-sigmatropic rearrangement
- α-propargyloxy acetic acid
ASJC Scopus subject areas
- Chemistry(all)
- Drug Discovery