TY - JOUR
T1 - Emergence of Metallic Conduction and Cobalt(II)-Based Single-Molecule Magnetism in the Same Temperature Range
AU - Shen, Yongbing
AU - Ito, Hiroshi
AU - Zhang, Haitao
AU - Yamochi, Hideki
AU - Cosquer, Goulven
AU - Herrmann, Carmen
AU - Ina, Toshiaki
AU - Yoshina, Shinji K.
AU - Breedlove, Brian K.
AU - Otsuka, Akihiro
AU - Ishikawa, Manabu
AU - Yoshida, Takefumi
AU - Yamashita, Masahiro
N1 - Publisher Copyright:
© 2021 American Chemical Society.
PY - 2021/4/7
Y1 - 2021/4/7
N2 - Single-molecule magnets exhibit magnetic bistabililties at the molecular level, making them promising for molecule-based spintronics due to high magnetic densities. The incorporation of SMM behavior and electrical conductivity in one compound is rare because these two physical properties often do not operate in the same temperature range, which further hinders their use in practical applications. Here we present an organic-inorganic molecular hybrid, β″-(BEDO-TTF)3[Co(pdms)2]·(MeCN)(H2O)2 (BO3) (BEDO-TTF = bis(ethylenedioxy)tetrathiafulvalene and H2pdms = 1,2-bis(methanesulfonamido)benzene), which manifests both metallic conduction (electrical conductivity up to 1000 S cm-1 at 12 K under 2.0 gigapascal pressure) and SMM behavior in the temperature range 12-26 K for the first time.
AB - Single-molecule magnets exhibit magnetic bistabililties at the molecular level, making them promising for molecule-based spintronics due to high magnetic densities. The incorporation of SMM behavior and electrical conductivity in one compound is rare because these two physical properties often do not operate in the same temperature range, which further hinders their use in practical applications. Here we present an organic-inorganic molecular hybrid, β″-(BEDO-TTF)3[Co(pdms)2]·(MeCN)(H2O)2 (BO3) (BEDO-TTF = bis(ethylenedioxy)tetrathiafulvalene and H2pdms = 1,2-bis(methanesulfonamido)benzene), which manifests both metallic conduction (electrical conductivity up to 1000 S cm-1 at 12 K under 2.0 gigapascal pressure) and SMM behavior in the temperature range 12-26 K for the first time.
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U2 - 10.1021/jacs.1c00455
DO - 10.1021/jacs.1c00455
M3 - Article
C2 - 33656871
AN - SCOPUS:85103477584
VL - 143
SP - 4891
EP - 4895
JO - Journal of the American Chemical Society
JF - Journal of the American Chemical Society
SN - 0002-7863
IS - 13
ER -