Electronic structures and dynamics of the excited triplet states of α,ω-diphenylpolyynes

Yasutomo Nagano, Tadaaki Ikoma, Kimio Akiyama, Shozo Tero-Kubota

Research output: Contribution to journalArticlepeer-review

28 Citations (Scopus)

Abstract

The molecular axes of x, y and z for the DPA and DPY molecules are defined as the out-of-plane axis, the short axis and the long axis within the molecular plane. It is experimentally determined that DPA and 1,4-diphenylbutadiyne (DPB) hold a linear planar structure belonging to the D2h point group in the ground (So) state. It is also reported that the triplet lifetimes for DPA, DPB, DPH and 1.8-DPO measured at 77K.

Original languageEnglish
Pages (from-to)1775-1784
Number of pages10
JournalJournal of Chemical Physics
Volume114
Issue number4
DOIs
Publication statusPublished - 2001 Jan 1

ASJC Scopus subject areas

  • Physics and Astronomy(all)
  • Physical and Theoretical Chemistry

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