@article{1ccf4f971346442eaf42586af05c309b,
title = "Electronic Structure of Carbon Dioxide in Sylgard-184 Evaluated by Using X-ray Emission Spectroscopy",
abstract = "To investigate the interactions between carbon dioxide (CO2) and Sylgard-184, which is mainly composed of polydimethylsiloxane and dimethylvinylated and trimethylated silica, the electronic structure of CO2 sorbed in Sylgard-184 was evaluated by using X-ray emission spectroscopy. The spectrum corresponding to the highest occupied molecular orbital of CO2 in the membrane showed a shoulder on the high energy side compared with that of CO2 gas, indicating that the symmetry of the electronic structure was disturbed owing to the interaction with Sylgard components.",
keywords = "Carbon dioxide, Polydimethylsiloxane, X-ray emission spectroscopy",
author = "Ryosuke Matsuno and Yokajaksusri Nutthon and Akira Miyano and Kakeru Ninomiya and Maiko Nishibori and Hisao Kiuchi and Shigenori Fujikawa and Yoshihisa Harada and Atsushi Takahara",
note = "Funding Information: This research is based on results obtained from a project, JPNP18016, commissioned by the New Energy and Industrial Technology Development Organization (NEDO). This work was carried out by joint research in the Synchrotron Radiation Research Organization and the Institute for Solid State Physics, the University of Tokyo (Proposal Nos. 2021AG14, 2021A7499). A Part of the experimental setup was financially supported by the JSPS KAKENHI Grant-in-Aid for Scientific Research on Innovative Areas: Aquatic Functional Materials (Grant No. JP19H05717). Publisher Copyright: {\textcopyright} 2022 The Chemical Society of Japan.",
year = "2022",
month = jun,
doi = "10.1246/cl.220113",
language = "English",
volume = "51",
pages = "650--653",
journal = "Chemistry Letters",
issn = "0366-7022",
publisher = "Chemical Society of Japan",
number = "6",
}