Electronic structure and dynamics of ionic species in thin poly(N-vinylcarbazole) films doped with some electron acceptors as revealed by transient absorption spectroscopy

T. Ueda, R. Fujisawa, H. Fukumura, A. Itaya, H. Masuhara

Research output: Contribution to journalArticlepeer-review

28 Citations (Scopus)

Abstract

A laser photolysis method, monitoring transient absorption under a multireflection condition, was applied to thin poly(N-vinylcarbazole) (PVCz) films doped with some electron acceptors. Absorption spectra composed of PVCz cation and acceptor anion were ascribed to migrating hole and trapped electron, respectively. The decay process of the ionic species obeyed second-order kinetics in the 1-40-μs range, indicating that homogeneous charge recombination is the rate-determining step for the decay of the ionic species. The diffusion coefficient of the hole obtained from the bimolecular rate constant decreased as the electron affinity of doped acceptors increased. The absorption band of the PVCz cation for the charge transfer system with large electron affinity was sharp compared with that of the exciplex system with a small one. These changes in the diffusion coefficient of the hole and in the absorption band of the PVCz cation were discussed in terms of electron-donor-acceptor interaction.

Original languageEnglish
Pages (from-to)3629-3635
Number of pages7
JournalJournal of physical chemistry
Volume99
Issue number11
DOIs
Publication statusPublished - 1995 Jan 1

ASJC Scopus subject areas

  • Engineering(all)
  • Physical and Theoretical Chemistry

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