Abstract
The fast sigmatropic [1,5]-Sn migration in cycloheptatrienyl(triphenyl)tin is effectively locked in the chromiumtricarbonyl complex. A much slower [1,3]-Sn + [1,2]-Cr diatropic rearrangement was detected by spin saturation transfer NMR.
Original language | English |
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Pages (from-to) | 14700-14701 |
Number of pages | 2 |
Journal | Journal of the American Chemical Society |
Volume | 125 |
Issue number | 48 |
DOIs | |
Publication status | Published - 2003 Dec 3 |
ASJC Scopus subject areas
- Catalysis
- Chemistry(all)
- Biochemistry
- Colloid and Surface Chemistry