"Electronic Lock" in Chromiumtricarbonyl Complex of Cycloheptatrienyltin

Ilya Gridnev, Oleg L. Tok

Research output: Contribution to journalArticlepeer-review

5 Citations (Scopus)

Abstract

The fast sigmatropic [1,5]-Sn migration in cycloheptatrienyl(triphenyl)tin is effectively locked in the chromiumtricarbonyl complex. A much slower [1,3]-Sn + [1,2]-Cr diatropic rearrangement was detected by spin saturation transfer NMR.

Original languageEnglish
Pages (from-to)14700-14701
Number of pages2
JournalJournal of the American Chemical Society
Volume125
Issue number48
DOIs
Publication statusPublished - 2003 Dec 3

ASJC Scopus subject areas

  • Catalysis
  • Chemistry(all)
  • Biochemistry
  • Colloid and Surface Chemistry

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