"Electronic Lock" in Chromiumtricarbonyl Complex of Cycloheptatrienyltin

Ilya Gridnev; Oleg L. Tok

doi:10.1021/ja0379621

"Electronic Lock" in Chromiumtricarbonyl Complex of Cycloheptatrienyltin

Ilya Gridnev, Oleg L. Tok

SCI - Chemistry

Research output: Contribution to journal › Article › peer-review

5 Citations (Scopus)

Abstract

The fast sigmatropic [1,5]-Sn migration in cycloheptatrienyl(triphenyl)tin is effectively locked in the chromiumtricarbonyl complex. A much slower [1,3]-Sn + [1,2]-Cr diatropic rearrangement was detected by spin saturation transfer NMR.

Original language	English
Pages (from-to)	14700-14701
Number of pages	2
Journal	Journal of the American Chemical Society
Volume	125
Issue number	48
DOIs	https://doi.org/10.1021/ja0379621
Publication status	Published - 2003 Dec 3

ASJC Scopus subject areas

Catalysis
Chemistry(all)
Biochemistry
Colloid and Surface Chemistry

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10.1021/ja0379621

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abstract = "The fast sigmatropic [1,5]-Sn migration in cycloheptatrienyl(triphenyl)tin is effectively locked in the chromiumtricarbonyl complex. A much slower [1,3]-Sn + [1,2]-Cr diatropic rearrangement was detected by spin saturation transfer NMR.",

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