Electronic decay processes following the resonance excitation of the B 1 s core electron in BF3

Kiyoshi Ueda, H. Chiba, Y. Sato, T. Hayaishi, E. Shigemasa, A. Yagishita

Research output: Contribution to journalArticlepeer-review

22 Citations (Scopus)

Abstract

Electron spectroscopy has been carried out to investigate spectator and participant resonance Auger decay processes following the B 1s→2a 2″ excitation in gaseous BF3 molecules using monochromatized synchrotron radiation. The resonance-enhanced satellite bands corresponding to the spectator Auger electron emission form six broad peaks showing good correspondence with the normal Auger bands. Resonance enhancement of the photolines corresponding to the participant Auger electron emission occurs only for the bonding orbitals having B character.

Original languageEnglish
Pages (from-to)3520-3523
Number of pages4
JournalThe Journal of Chemical Physics
Volume101
Issue number5
DOIs
Publication statusPublished - 1994 Jan 1

ASJC Scopus subject areas

  • Physics and Astronomy(all)
  • Physical and Theoretical Chemistry

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