Electronic Band Structure of C8Cs Studied by Highly-Angle-Resolved Ultraviolet Photoelectron Spectroscopy

Nihal Gunasekara, Takashi Takahashi, Fumihiko Maeda, Takasi Sagawa, Hiroyoshi Suematsu

Research output: Contribution to journalArticlepeer-review

8 Citations (Scopus)

Abstract

The electronic band structure of the first-stage cesium-intercalated graphite C8Cs was determined by the highly-angle-resolved ultraviolet photoelectron spectroscopy. We found a prominent energy dispersion of the π∗ band at K point for the first time. The experimentally-estimated electron occupancy of the π∗ band is 0.45 ±0.05 unit electronic charge. This strongly suggests that another half of a unit electronic charge is accommodated in the interlayer band at the Γ point. The present experimental results have been compared with the theoretical band calculations presented so far as well as with the recently reported experimental results on Cs overlay er on graphite.

Original languageEnglish
Pages (from-to)2581-2589
Number of pages9
Journaljournal of the physical society of japan
Volume56
Issue number7
DOIs
Publication statusPublished - 1987 Jan 1

ASJC Scopus subject areas

  • Physics and Astronomy(all)

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