Electron irradiation-induced structural transformation in metallic glasses

E. G. Fu; Jesse Carter; Michael Martin; Guoqiang Xie; X. Zhang; Y. Q. Wang; Rick Littleton; Lin Shao

doi:10.1016/j.scriptamat.2009.03.001

Electron irradiation-induced structural transformation in metallic glasses

E. G. Fu, Jesse Carter, Michael Martin, Guoqiang Xie, X. Zhang, Y. Q. Wang, Rick Littleton, Lin Shao

Research output: Contribution to journal › Article › peer-review

24 Citations (Scopus)

Abstract

Microstructural evolution of Zr₅₅Cu₃₀Al₁₀Ni₅ and Cu₅₀Zr₄₅Ti₅ metallic glasses under 200 keV electron irradiation has been studied in situ by transmission electron microscopy. Zr₅₅Cu₃₀Al₁₀Ni₅, which has a wider supercooled liquid region, is found to be stable under electron irradiation and no crystallization is observed up to an irradiation fluence of 8.7 × 10²⁶ electrons m^-2. In contrast, nanometer size crystalline Cu₁₀Zr₇ phases are formed in Cu₅₀Zr₄₅Ti₅ under electron irradiation. The partial crystallization is attributed to irradiation enhanced atomic mobility.

Original language	English
Pages (from-to)	40-43
Number of pages	4
Journal	Scripta Materialia
Volume	61
Issue number	1
DOIs	https://doi.org/10.1016/j.scriptamat.2009.03.001
Publication status	Published - 2009 Jul

Keywords

Metallic glasses
Recrystallization

ASJC Scopus subject areas

Materials Science(all)
Condensed Matter Physics
Mechanics of Materials
Mechanical Engineering
Metals and Alloys

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10.1016/j.scriptamat.2009.03.001

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title = "Electron irradiation-induced structural transformation in metallic glasses",

abstract = "Microstructural evolution of Zr55Cu30Al10Ni5 and Cu50Zr45Ti5 metallic glasses under 200 keV electron irradiation has been studied in situ by transmission electron microscopy. Zr55Cu30Al10Ni5, which has a wider supercooled liquid region, is found to be stable under electron irradiation and no crystallization is observed up to an irradiation fluence of 8.7 × 1026 electrons m-2. In contrast, nanometer size crystalline Cu10Zr7 phases are formed in Cu50Zr45Ti5 under electron irradiation. The partial crystallization is attributed to irradiation enhanced atomic mobility.",

keywords = "Metallic glasses, Recrystallization",

author = "Fu, {E. G.} and Jesse Carter and Michael Martin and Guoqiang Xie and X. Zhang and Wang, {Y. Q.} and Rick Littleton and Lin Shao",

note = "Funding Information: This work was financially supported by the University Embryonic Technologies Program from Siemens Power Generation Emerging Technologies. L.S. acknowledges the support from the NRC Early Career Development Grant and the access to the user facilities at DOE-Center for Integrated Nanotechnologies (CINT). X.Z. acknowledges the support by DOE under grant number DE-FC07-05ID14657. Los Alamos National Laboratory, an affirmative action equal opportunity employer, is operated by Los Alamos National Security, LLC, for the National Nuclear Security Administration of the U.S. Department of Energy under contract DE-AC52-06NA25396.",

year = "2009",

month = jul,

doi = "10.1016/j.scriptamat.2009.03.001",

language = "English",

volume = "61",

pages = "40--43",

journal = "Scripta Materialia",

issn = "1359-6462",

publisher = "Elsevier Limited",

number = "1",

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T1 - Electron irradiation-induced structural transformation in metallic glasses

AU - Fu, E. G.

AU - Carter, Jesse

AU - Martin, Michael

AU - Xie, Guoqiang

AU - Zhang, X.

AU - Wang, Y. Q.

AU - Littleton, Rick

AU - Shao, Lin

N1 - Funding Information: This work was financially supported by the University Embryonic Technologies Program from Siemens Power Generation Emerging Technologies. L.S. acknowledges the support from the NRC Early Career Development Grant and the access to the user facilities at DOE-Center for Integrated Nanotechnologies (CINT). X.Z. acknowledges the support by DOE under grant number DE-FC07-05ID14657. Los Alamos National Laboratory, an affirmative action equal opportunity employer, is operated by Los Alamos National Security, LLC, for the National Nuclear Security Administration of the U.S. Department of Energy under contract DE-AC52-06NA25396.

PY - 2009/7

Y1 - 2009/7

N2 - Microstructural evolution of Zr55Cu30Al10Ni5 and Cu50Zr45Ti5 metallic glasses under 200 keV electron irradiation has been studied in situ by transmission electron microscopy. Zr55Cu30Al10Ni5, which has a wider supercooled liquid region, is found to be stable under electron irradiation and no crystallization is observed up to an irradiation fluence of 8.7 × 1026 electrons m-2. In contrast, nanometer size crystalline Cu10Zr7 phases are formed in Cu50Zr45Ti5 under electron irradiation. The partial crystallization is attributed to irradiation enhanced atomic mobility.

AB - Microstructural evolution of Zr55Cu30Al10Ni5 and Cu50Zr45Ti5 metallic glasses under 200 keV electron irradiation has been studied in situ by transmission electron microscopy. Zr55Cu30Al10Ni5, which has a wider supercooled liquid region, is found to be stable under electron irradiation and no crystallization is observed up to an irradiation fluence of 8.7 × 1026 electrons m-2. In contrast, nanometer size crystalline Cu10Zr7 phases are formed in Cu50Zr45Ti5 under electron irradiation. The partial crystallization is attributed to irradiation enhanced atomic mobility.

KW - Metallic glasses

KW - Recrystallization

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JO - Scripta Materialia

JF - Scripta Materialia

SN - 1359-6462

IS - 1

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Electron irradiation-induced structural transformation in metallic glasses

Abstract

Keywords

ASJC Scopus subject areas

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