Electrochemistry of viologen-containing Langmuir-Blodgett film prepared by polyion complex technique

Masatsugu Shimomura; Kennichi Kasuga; Takashi Tsukada

doi:10.1016/0040-6090(92)90261-9

Electrochemistry of viologen-containing Langmuir-Blodgett film prepared by polyion complex technique

Masatsugu Shimomura, Kennichi Kasuga, Takashi Tsukada

Research output: Contribution to journal › Article

12 Citations (Scopus)

Abstract

Due to the electrostatic interaction at the air-water interface, a stable monolayer of a water-soluble viologen amphiphile was formed on an aqueous solution of a counter charged polymer. Pressure-area isotherms of the polyion-complexed monolayers were strongly dependent on the chemical structure of the aniomic polymers. The polyion-complexed monolayers were transferred on an ITO electrode as Langmuir-Blodgett films. The redox potential of the polyion-complexed LB film was also dependent on the chemical structure, especially the charge density, of the polymers.

Original language	English
Pages (from-to)	375-377
Number of pages	3
Journal	Thin Solid Films
Volume	210-211
Issue number	PART 1
DOIs	https://doi.org/10.1016/0040-6090(92)90261-9
Publication status	Published - 1992 Apr 15

ASJC Scopus subject areas

Electronic, Optical and Magnetic Materials
Surfaces and Interfaces
Surfaces, Coatings and Films
Metals and Alloys
Materials Chemistry

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T1 - Electrochemistry of viologen-containing Langmuir-Blodgett film prepared by polyion complex technique

AU - Shimomura, Masatsugu

AU - Kasuga, Kennichi

AU - Tsukada, Takashi

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Y1 - 1992/4/15

N2 - Due to the electrostatic interaction at the air-water interface, a stable monolayer of a water-soluble viologen amphiphile was formed on an aqueous solution of a counter charged polymer. Pressure-area isotherms of the polyion-complexed monolayers were strongly dependent on the chemical structure of the aniomic polymers. The polyion-complexed monolayers were transferred on an ITO electrode as Langmuir-Blodgett films. The redox potential of the polyion-complexed LB film was also dependent on the chemical structure, especially the charge density, of the polymers.

AB - Due to the electrostatic interaction at the air-water interface, a stable monolayer of a water-soluble viologen amphiphile was formed on an aqueous solution of a counter charged polymer. Pressure-area isotherms of the polyion-complexed monolayers were strongly dependent on the chemical structure of the aniomic polymers. The polyion-complexed monolayers were transferred on an ITO electrode as Langmuir-Blodgett films. The redox potential of the polyion-complexed LB film was also dependent on the chemical structure, especially the charge density, of the polymers.

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