Electrochemical synthesis and structure of the first example of a ferrocene dication: Propane-1,3-diyl-1,1′-bis(tetramethylcyclopentadienyl)iron(2+)

Hiroshi Ogino, Hiromi Tobita, Hiroki Habazaki, Mamoru Shimoi

Research output: Contribution to journalArticlepeer-review

11 Citations (Scopus)

Abstract

The permethylferrocenophane [(pdmcp)Fe] [pdmcp = η5, η5-C5Me4(CH2)3C 5Me4] and its oxidised species, monocation and dication salts, were synthesised, in which the latter, [(pdmcp)Fe(NCMe)](PF 6)2, has a substantially bent bis(cyclopentadienyl) moiety to accommodate one molecule of MeCN.

Original languageEnglish
Pages (from-to)828-829
Number of pages2
JournalJournal of the Chemical Society, Chemical Communications
Issue number13
DOIs
Publication statusPublished - 1989 Jan 1

ASJC Scopus subject areas

  • Molecular Medicine

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