TY - JOUR
T1 - Electrochemical in situ conductivity measurement of C60 films in acetonitrile containing M(bpy)32+ (M Fe, Ni, Ru, or Os)
AU - Nishizawa, Matsuhiko
AU - Tomura, Keiji
AU - Matsue, Tomokazu
AU - Uchida, Isamu
PY - 1994/12/12
Y1 - 1994/12/12
N2 - The electrochemical behavior and electrical conductivity of C60 thin films were studied in acetonitrile containing M(bpy)32+ (M Fe, Ni, Ru or Os; bpy 2,2′-bipyridine). Cyclic voltammetry of C60 films showed stable reduction-reoxidation waves. In situ conductivity measurements indicated that an enhanced conductivity (on the order of 10-2 S cm-) appeared reversibly on electrochemical reduction accompanied by doping of M(bpy)32+ ions into the C60 films. The electrochemical reduction also induced some structural change.
AB - The electrochemical behavior and electrical conductivity of C60 thin films were studied in acetonitrile containing M(bpy)32+ (M Fe, Ni, Ru or Os; bpy 2,2′-bipyridine). Cyclic voltammetry of C60 films showed stable reduction-reoxidation waves. In situ conductivity measurements indicated that an enhanced conductivity (on the order of 10-2 S cm-) appeared reversibly on electrochemical reduction accompanied by doping of M(bpy)32+ ions into the C60 films. The electrochemical reduction also induced some structural change.
KW - Conductivity
KW - Fullerene films
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U2 - 10.1016/0022-0728(94)87143-4
DO - 10.1016/0022-0728(94)87143-4
M3 - Article
AN - SCOPUS:0000978834
VL - 379
SP - 233
EP - 237
JO - Journal of Electroanalytical Chemistry
JF - Journal of Electroanalytical Chemistry
SN - 1572-6657
IS - 1-2
ER -