TY - JOUR
T1 - Electrochemical Impedance Spectroscopy of High-Efficiency Hydrogen Membrane Fuel Cells Based on Sputter-Deposited BaCe0.8Y0.2O3-δ Thin Films
AU - Aoki, Yoshitaka
AU - Kobayashi, Shohei
AU - Yamaguchi, Tomoyuki
AU - Tsuji, Etsushi
AU - Habazaki, Hiroki
AU - Yashiro, Keiji
AU - Kawada, Tetsuya
AU - Ohtsuka, Toshiaki
N1 - Funding Information:
This research was supported by JST, PRESTO, "Creation of innovative core technology for manufacture and use of energy carriers from renewable energy" program. This work was conducted at Hokkaido University, supported by "Nanotechnology Platform" Program of the MEXT Japan.
Publisher Copyright:
© 2016 American Chemical Society.
PY - 2016/7/28
Y1 - 2016/7/28
N2 - A hydrogen membrane fuel cell (HMFC) consisting of a Pd solid anode, 1 μm thick BaCe0.8Y0.2O3-δ thin-film electrolyte, and La0.6Sr0.4Co0.2Fe0.8O3 cathode was examined. A single-phase BaCe0.8Y0.2O3-δ thin film was successfully deposited by radio frequency cosputtering with BaCe0.8Y0.2O3 and Ce0.9Y0.1O2 double targets, as checked by X-ray diffraction, transmission electron microscopy, and wavelength dispersive X-ray analysis. The maximum power density reached 1.05 W cm-2 at 600 °C, and this value was higher than the champion data of the recently reported proton-conducting ceramic fuel cells (PCFCs). Electrochemical impedance analysis was performed to characterize the anode and cathode polarization behavior. The impedance responses of HMFC were explicable with an equivalent circuit built by a series connection of cathode charge-transfer elements and anode mass-transfer elements. The contribution of the mass transfer in Pd bulk was found to be relatively small in comparison to cathode polarization and ohmic loss in normal fuel cell atmosphere. Moreover, the cathodic charge-transfer resistance of HMFC was found to be 25 times smaller than those of the recent PCFC systems. The current results demonstrated that the HMFC retained relatively large gas-proton-electron triple-boundary zones near the interface between the BaCe0.8Y0.2O3-δ electrolyte and porous La0.6Sr0.4Co0.2Fe0.8O3-δ cathode.
AB - A hydrogen membrane fuel cell (HMFC) consisting of a Pd solid anode, 1 μm thick BaCe0.8Y0.2O3-δ thin-film electrolyte, and La0.6Sr0.4Co0.2Fe0.8O3 cathode was examined. A single-phase BaCe0.8Y0.2O3-δ thin film was successfully deposited by radio frequency cosputtering with BaCe0.8Y0.2O3 and Ce0.9Y0.1O2 double targets, as checked by X-ray diffraction, transmission electron microscopy, and wavelength dispersive X-ray analysis. The maximum power density reached 1.05 W cm-2 at 600 °C, and this value was higher than the champion data of the recently reported proton-conducting ceramic fuel cells (PCFCs). Electrochemical impedance analysis was performed to characterize the anode and cathode polarization behavior. The impedance responses of HMFC were explicable with an equivalent circuit built by a series connection of cathode charge-transfer elements and anode mass-transfer elements. The contribution of the mass transfer in Pd bulk was found to be relatively small in comparison to cathode polarization and ohmic loss in normal fuel cell atmosphere. Moreover, the cathodic charge-transfer resistance of HMFC was found to be 25 times smaller than those of the recent PCFC systems. The current results demonstrated that the HMFC retained relatively large gas-proton-electron triple-boundary zones near the interface between the BaCe0.8Y0.2O3-δ electrolyte and porous La0.6Sr0.4Co0.2Fe0.8O3-δ cathode.
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U2 - 10.1021/acs.jpcc.5b12593
DO - 10.1021/acs.jpcc.5b12593
M3 - Article
AN - SCOPUS:84979924139
VL - 120
SP - 15976
EP - 15985
JO - Journal of Physical Chemistry C
JF - Journal of Physical Chemistry C
SN - 1932-7447
IS - 29
ER -