Electrochemical epitaxial growth of a Pt(111) phase on an Au(111) electrode

Kohei Uosaki, Shen Ye, Hideo Naohara, Yasuhiro Oda, Toshio Haba, Toshihiro Kondo

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112 Citations (Scopus)

Abstract

The electrochemical deposition of platinum on an Au(111) single-crystal electrode in acidic solutions containing H2PtCl6 was studied using an electrochemical scanning tunneling microscope (STM) and electrochemical quartz crystal microbalance (EQCM). The STM investigation showed an ordered adlayer of PtCl62- on the electrode surface during the electrochemical deposition of platinum and a Pt(111)-(1×1) structure on the electrode surface after the electrode was rinsed with a Pt complex-free solution. Formations of the Pt(111) bulk phase and surface structure of Pt(111)-(1×1) were confirmed by X-ray diffraction (XRD) and the underpotential deposition of copper and hydrogen, respectively.

Original languageEnglish
Pages (from-to)7566-7572
Number of pages7
JournalJournal of Physical Chemistry B
Volume101
Issue number38
Publication statusPublished - 1997 Sep 18
Externally publishedYes

ASJC Scopus subject areas

  • Physical and Theoretical Chemistry
  • Surfaces, Coatings and Films
  • Materials Chemistry

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  • Cite this

    Uosaki, K., Ye, S., Naohara, H., Oda, Y., Haba, T., & Kondo, T. (1997). Electrochemical epitaxial growth of a Pt(111) phase on an Au(111) electrode. Journal of Physical Chemistry B, 101(38), 7566-7572.