Electrochemical control of a non-covalent binding between ferrocene and beta-cyclodextrin

V. Kolivoška, M. Mohos, I. V. Pobelov, S. Rohrbach, K. Yoshida, W. J. Hong, Y. C. Fu, P. Moreno-Garcüa, G. Mészáros, P. Broekmann, M. Hromadová, R. Sokolová, M. Valášek, Th Wandlowski

    Research output: Contribution to journalArticlepeer-review

    20 Citations (Scopus)

    Abstract

    The forces required for the detachment of ferrocene (Fc) from β-cyclodextrin (βCD) in a single host (βCD)-guest (Fc) complex were investigated using force spectroscopy under electrochemical conditions. The redox state of the guest Fc moiety as well as the structure of the supporting matrix was found to decisively affect the nanomechanical properties of the complex.

    Original languageEnglish
    Pages (from-to)11757-11759
    Number of pages3
    JournalChemical Communications
    Volume50
    Issue number79
    DOIs
    Publication statusPublished - 2014 Sep 9

    ASJC Scopus subject areas

    • Catalysis
    • Electronic, Optical and Magnetic Materials
    • Ceramics and Composites
    • Chemistry(all)
    • Surfaces, Coatings and Films
    • Metals and Alloys
    • Materials Chemistry

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