Electrochemical capacitance of self-ordered mesoporous carbon

Haoshen Zhou; Shenmin Zhu; Mitsuhiro Hibino; Itaru Honma

doi:10.1016/S0378-7753(03)00439-7

Electrochemical capacitance of self-ordered mesoporous carbon

Haoshen Zhou, Shenmin Zhu, Mitsuhiro Hibino, Itaru Honma

Research output: Contribution to journal › Article › peer-review

217 Citations (Scopus)

Abstract

The capacitance properties of the self-ordered mesoporous carbons (CMK-3), from a template of hexagonal self-ordered mesoporous SiO₂ (SBA15) using sucrose as the carbon source, have been investigated. The pore distribution was narrow with a diameter of 3.90 nm and a surface area of 900 m²/g. Rectangular shape of the cyclic voltammetry was observed even if the scan rate is increased to about 5 × 10^-2V/s. Self-ordered mesoporous carbon exhibited a electrochemical double-layer capacitance of 60-90 F/g in scan rate from 5 × 10^-4 to 5 × 10^-2V/s between 1.5 and 3.4 V (Li/Li⁺). The specific capacitance of 10 μF/cm² was similar to that of the typical value of EDLC. After the 100th cycle, the capacity decreased 20% in comparing with that of the first one.

Original language	English
Pages (from-to)	219-223
Number of pages	5
Journal	Journal of Power Sources
Volume	122
Issue number	2
DOIs	https://doi.org/10.1016/S0378-7753(03)00439-7
Publication status	Published - 2003 Jul 23
Externally published	Yes

Keywords

Electrochemical double-layer capacitors
Mesoporous carbon
Self-ordered

ASJC Scopus subject areas

Renewable Energy, Sustainability and the Environment
Energy Engineering and Power Technology
Physical and Theoretical Chemistry
Electrical and Electronic Engineering

UN SDGs

This output contributes to the following UN Sustainable Development Goals (SDGs)

Access to Document

10.1016/S0378-7753(03)00439-7

Cite this

@article{5111baebff6a4a3188862d46b49ae8e6,

title = "Electrochemical capacitance of self-ordered mesoporous carbon",

abstract = "The capacitance properties of the self-ordered mesoporous carbons (CMK-3), from a template of hexagonal self-ordered mesoporous SiO2 (SBA15) using sucrose as the carbon source, have been investigated. The pore distribution was narrow with a diameter of 3.90 nm and a surface area of 900 m2/g. Rectangular shape of the cyclic voltammetry was observed even if the scan rate is increased to about 5 × 10-2V/s. Self-ordered mesoporous carbon exhibited a electrochemical double-layer capacitance of 60-90 F/g in scan rate from 5 × 10-4 to 5 × 10-2V/s between 1.5 and 3.4 V (Li/Li+). The specific capacitance of 10 μF/cm2 was similar to that of the typical value of EDLC. After the 100th cycle, the capacity decreased 20% in comparing with that of the first one.",

keywords = "Electrochemical double-layer capacitors, Mesoporous carbon, Self-ordered",

author = "Haoshen Zhou and Shenmin Zhu and Mitsuhiro Hibino and Itaru Honma",

year = "2003",

month = jul,

day = "23",

doi = "10.1016/S0378-7753(03)00439-7",

language = "English",

volume = "122",

pages = "219--223",

journal = "Journal of Power Sources",

issn = "0378-7753",

publisher = "Elsevier",

number = "2",

}

TY - JOUR

T1 - Electrochemical capacitance of self-ordered mesoporous carbon

AU - Zhou, Haoshen

AU - Zhu, Shenmin

AU - Hibino, Mitsuhiro

AU - Honma, Itaru

PY - 2003/7/23

Y1 - 2003/7/23

N2 - The capacitance properties of the self-ordered mesoporous carbons (CMK-3), from a template of hexagonal self-ordered mesoporous SiO2 (SBA15) using sucrose as the carbon source, have been investigated. The pore distribution was narrow with a diameter of 3.90 nm and a surface area of 900 m2/g. Rectangular shape of the cyclic voltammetry was observed even if the scan rate is increased to about 5 × 10-2V/s. Self-ordered mesoporous carbon exhibited a electrochemical double-layer capacitance of 60-90 F/g in scan rate from 5 × 10-4 to 5 × 10-2V/s between 1.5 and 3.4 V (Li/Li+). The specific capacitance of 10 μF/cm2 was similar to that of the typical value of EDLC. After the 100th cycle, the capacity decreased 20% in comparing with that of the first one.

AB - The capacitance properties of the self-ordered mesoporous carbons (CMK-3), from a template of hexagonal self-ordered mesoporous SiO2 (SBA15) using sucrose as the carbon source, have been investigated. The pore distribution was narrow with a diameter of 3.90 nm and a surface area of 900 m2/g. Rectangular shape of the cyclic voltammetry was observed even if the scan rate is increased to about 5 × 10-2V/s. Self-ordered mesoporous carbon exhibited a electrochemical double-layer capacitance of 60-90 F/g in scan rate from 5 × 10-4 to 5 × 10-2V/s between 1.5 and 3.4 V (Li/Li+). The specific capacitance of 10 μF/cm2 was similar to that of the typical value of EDLC. After the 100th cycle, the capacity decreased 20% in comparing with that of the first one.

KW - Electrochemical double-layer capacitors

KW - Mesoporous carbon

KW - Self-ordered

UR - http://www.scopus.com/inward/record.url?scp=0038391515&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=0038391515&partnerID=8YFLogxK

U2 - 10.1016/S0378-7753(03)00439-7

DO - 10.1016/S0378-7753(03)00439-7

M3 - Article

AN - SCOPUS:0038391515

VL - 122

SP - 219

EP - 223

JO - Journal of Power Sources

JF - Journal of Power Sources

SN - 0378-7753

IS - 2

ER -

Electrochemical capacitance of self-ordered mesoporous carbon

Abstract

Keywords

ASJC Scopus subject areas

UN SDGs

Access to Document

Other files and links

Fingerprint

Cite this