Electrochemical and spectroelectrochemical behaviour of Np(VI) ions in nitric acid solutions

Seong Yun Kim, Toshihide Asakura, Yasuji Morita

Research output: Contribution to journalArticlepeer-review

11 Citations (Scopus)

Abstract

Electrochemical and spectroelectrochemical has been used to investigate the behaviour of neptunium (VI) in 1-8 M HNO3 solutions. The electrochemical reactions of Np(VI) ions were found to occur quasi-reversibly. The formal redox potentials (E°) for Np(VI)/Np(V) couples were determined to be +0.906, +0.908, +0.909, +0.902, +0.896, +0.895, +0.888, and +0.884V (vs. Ag/AgCl) for Np(VI) ions in 1, 2, 3, 4, 5, 6, 7, 8 M HNO3 solutions, respectively. The reduction processes of Np(VI) ions were followed spectroelectrochemically by using an optical transparent thin layer electrode cell. It was found that the absorption spectra measured at the applied potentials from +1.10 to +0.60 V versus Ag/AgCl reference electrode redox couple for Np(VI) in HNO3 solution have clear isosbestic points. These results indicate that the only reduction product of Np(VI) is Np(V), which is of considerable stability in HNO3 solutions.

Original languageEnglish
Pages (from-to)767-770
Number of pages4
JournalRadiochimica Acta
Volume93
Issue number12
DOIs
Publication statusPublished - 2005 Dec 27
Externally publishedYes

Keywords

  • Cyclic voltammetry
  • Electrochemistry
  • Neptunium
  • Redox reaction
  • Spectroelectrochemistry

ASJC Scopus subject areas

  • Physical and Theoretical Chemistry

Fingerprint Dive into the research topics of 'Electrochemical and spectroelectrochemical behaviour of Np(VI) ions in nitric acid solutions'. Together they form a unique fingerprint.

Cite this