Electrocatalytic Oxidation of Amines to Nitriles on a TEMPO-modified Graphite Felt Electrode (TEMPO = 2,2,6,6-tetramethylpiperidin-1-yloxyl)

Yoshitomo Kashiwagi; Futoshi Kurashima; Chikara Kikuchi; Junichi Anzai; Tetsuo Osa; James M. Bobbitt

doi:10.1002/jccs.199800023

Electrocatalytic Oxidation of Amines to Nitriles on a TEMPO-modified Graphite Felt Electrode (TEMPO = 2,2,6,6-tetramethylpiperidin-1-yloxyl)

Yoshitomo Kashiwagi, Futoshi Kurashima, Chikara Kikuchi, Junichi Anzai, Tetsuo Osa, James M. Bobbitt

PHA - Molecular Pharmaceutical Science

Research output: Contribution to journal › Article › peer-review

15 Citations (Scopus)

Abstract

Preparative electrocalalytic oxidation of amines to nitriles was successfully achieved on a poly (acrylic acid)-coated graphite felt electrode immobilizing 4-amino-2,2,6,6-tetramethylpiperidin-1-yloxyl in high selectivity (> 95% ) and high current efficiency (> 92%).

Original language	English
Pages (from-to)	135-138
Number of pages	4
Journal	Journal of the Chinese Chemical Society
Volume	45
Issue number	1
DOIs	https://doi.org/10.1002/jccs.199800023
Publication status	Published - 1998 Jan 1

Keywords

Amine
Mediator
Modified electrode
Nitrile
TEMPO

ASJC Scopus subject areas

Chemistry(all)

Access to Document

10.1002/jccs.199800023

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Electrocatalytic Oxidation of Amines to Nitriles on a TEMPO-modified Graphite Felt Electrode (TEMPO = 2,2,6,6-tetramethylpiperidin-1-yloxyl). / Kashiwagi, Yoshitomo; Kurashima, Futoshi; Kikuchi, Chikara; Anzai, Junichi; Osa, Tetsuo; Bobbitt, James M.

In: Journal of the Chinese Chemical Society, Vol. 45, No. 1, 01.01.1998, p. 135-138.

Research output: Contribution to journal › Article › peer-review

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