Electrocatalytic Hydrogenation of Olefins Using Palladium Meta Microparticles Deposited on Viologen Film-coated Graphite Felt

Yoshitomo Kashiwagi, Norihiko Shibayama, Jun Ichi Anzai, Tetsuo Osa

Research output: Contribution to journalArticlepeer-review

6 Citations (Scopus)

Abstract

Palladium (Pd) metal microparticles were deposited in a viologen-containing polymer layer on the surface of a graphite felt electrode. The Pd-deposited electrode is effective for the electrocatalytic hydrogenation of the carbon-carbon double bond part of alkyl olefins (1-hexene, 1-decene, cis-2-penetene), conjugated enones (2-cyclohexene-1-one, 4-isopropyl-2-cyclohexene-1-one, 3,5,5-trimetyl-2-cyclohexene-1-one), styrene, and transstilbene with 100 % selectivity.

Original languageEnglish
Pages (from-to)42-45
Number of pages4
JournalElectrochemistry
Volume68
Issue number1
DOIs
Publication statusPublished - 2000
Externally publishedYes

Keywords

  • Electrocatalytic Hydrogenation
  • Pd-deposited Electrode
  • Viologen Film-coated Graphite Felt Electrode

ASJC Scopus subject areas

  • Electrochemistry

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