Electrically Switchable Amplified Spontaneous Emission from Liquid Crystalline Phase of an AIEE-Active ESIPT Molecule

Yusuke Tsutsui, Wanying Zhang, Samrat Ghosh, Tsuneaki Sakurai, Hiroyuki Yoshida, Masanori Ozaki, Tomoyuki Akutagawa, Shu Seki

    Research output: Contribution to journalArticlepeer-review

    12 Citations (Scopus)


    Use of organic molecules as lasing media has much potential to develop next-generation optical devices as soft-matter photonics with wideband tunability and large coherence area. Although mirrorless lasing was theoretically predicted and practically demonstrated in helical cholesteric liquid crystalline (LC) phases of organic compounds, recent studies on optical confinement have been much focused into hard-crystalline phases of the molecules. Aggregation-induced emission (AIE) and enhancement (AIEE) provides one of the optimal molecular systems for light amplification in condensed phases, and herein AIEE activity and excited-state intramolecular proton transfer (ESIPT) are successfully coupled in a room temperature (RT) nematic LC. Suppressing the effect of concentration quenching/self-absorption and attaining four-level system for population inversion by the combination of AIEE and ESIPT in LC phases, lead to the amplified spontaneous emission (ASE) from a newly designed molecule: C5Ph-HBT dispersed in RT LC matrix with the pumping energy threshold of 20 mJ cm–2. Moreover, the nematic LC allows the orientation of the molecular dipoles in response to external electric fields. Hence, the fluorescence as well as the ASE switching is attained at RT, demonstrating the potential of these composite materials as “switchable” ASE media for technological progress.

    Original languageEnglish
    Article number1902158
    JournalAdvanced Optical Materials
    Issue number14
    Publication statusPublished - 2020 Jul 1


    • aggregation-induced emission
    • amplified spontaneous emission
    • excited-state intramolecular proton transfer
    • fluorescence
    • liquid crystals
    • switchable lasing

    ASJC Scopus subject areas

    • Electronic, Optical and Magnetic Materials
    • Atomic and Molecular Physics, and Optics


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