Electrical conduction of halogen-bridged metal complexes Ni 1-xPdx(chxn)2Br3

Hiroshi Ito, Makoto Sunata, Shin Ichi Kuroda, Toshio Manabe, Masahiro Yamashita

Research output: Contribution to journalArticle

6 Citations (Scopus)

Abstract

The resistance and thermopower of the quasi-one-dimensional halogen-bridged metal complexes Ni1-xPdx(chxn)2Br3 are studied. Pressure dependence of the resistance indicates the crossover from SDW state to CDW state at x=0.84-0.95. For almost all x region, thermopower is negative. For x<0.5, thermopower is independent of temperature, while it is semiconducting for x>0.6.

Original languageEnglish
Pages (from-to)285-290
Number of pages6
JournalMolecular Crystals and Liquid Crystals Science and Technology Section A: Molecular Crystals and Liquid Crystals
Volume379
Publication statusPublished - 2002 Dec 1
Externally publishedYes

Keywords

  • Anisotropy
  • Halogen-bridged metal complex
  • Pressure
  • Resistance
  • Thermopower

ASJC Scopus subject areas

  • Condensed Matter Physics

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