Efficient synthesis of multisubstituted 2-alkenylpyridines via 2,3-rearrangement of O -homoallenylic oximes

Itaru Nakamura, Yoshiharu Oyama, Dong Zhang, Masahiro Terada

Research output: Contribution to journalArticlepeer-review

8 Citations (Scopus)

Abstract

O-Homoallenylic α,β-unsaturated oximes were efficiently converted to the corresponding 2-alkenylpyridine derivatives by microwave irradiation. The present reaction proceeds via 2,3-rearrangement followed by 6π-electrocyclization of the resulting N-(2-dienyl)nitrone intermediate serving as a 3-azatriene.

Original languageEnglish
Pages (from-to)1034-1036
Number of pages3
JournalOrganic Chemistry Frontiers
Volume4
Issue number6
DOIs
Publication statusPublished - 2017 Jun

ASJC Scopus subject areas

  • Organic Chemistry

Fingerprint Dive into the research topics of 'Efficient synthesis of multisubstituted 2-alkenylpyridines via 2,3-rearrangement of O -homoallenylic oximes'. Together they form a unique fingerprint.

Cite this