Efficient synthesis of eight-membered nitrogen heterocycles from O-propargylic oximes by rhodium-catalyzed cascade reactions

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21 Citations (Scopus)

Abstract

Azocine derivatives were successfully synthesized from O-propargylic oximes by means of a Rh-catalyzed 2,3-rearrangement/heterocyclization cascade reaction. Moreover, the chirality of the substrate was maintained throughout the cascade process to afford the corresponding optically active azocines.

Original languageEnglish
Pages (from-to)10214-10219
Number of pages6
JournalChemistry - A European Journal
Volume20
Issue number33
DOIs
Publication statusPublished - 2014 Aug 11

Keywords

  • cascade reactions
  • chirality
  • nitrogen heterocycles
  • rearrangement
  • rhodium

ASJC Scopus subject areas

  • Catalysis
  • Organic Chemistry

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