Effects of quartz addition on the mechanochemical dechlorination of chlorobiphenyl by using CaO

Kibu Chiyo; Fumio Saito; Tadaaki Ikoma; Shozo Tero-Kubota; Kiyotaka Hatakeda

doi:10.1021/es010638q

Effects of quartz addition on the mechanochemical dechlorination of chlorobiphenyl by using CaO

Kibu Chiyo, Fumio Saito, Tadaaki Ikoma, Shozo Tero-Kubota, Kiyotaka Hatakeda

Division of Process and System Engineering

Research output: Contribution to journal › Article › peer-review

88 Citations (Scopus)

Abstract

Grinding a mixture of 3-chlorobiphenyl (BP-Cl) and CaO with or without the addition of quartz was conducted in air by a planetary ball mill to investigate the mechanochemical dechlorination of BP-Cl. The dechlorinating reaction proceeds with an increase in grinding time, and over 99% of BP-Cl is decomposed at 360 min. Washing the ground sample with different solvents results in different products. Addition of quartz to the grinding mixture facilitates dechlorination efficiency, especially in the case of a high weight ratio of BP-Cl to CaO.

Original language	English
Pages (from-to)	4933-4935
Number of pages	3
Journal	Environmental Science and Technology
Volume	35
Issue number	24
DOIs	https://doi.org/10.1021/es010638q
Publication status	Published - 2001 Dec 15

ASJC Scopus subject areas

Chemistry(all)
Environmental Chemistry

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10.1021/es010638q

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abstract = "Grinding a mixture of 3-chlorobiphenyl (BP-Cl) and CaO with or without the addition of quartz was conducted in air by a planetary ball mill to investigate the mechanochemical dechlorination of BP-Cl. The dechlorinating reaction proceeds with an increase in grinding time, and over 99% of BP-Cl is decomposed at 360 min. Washing the ground sample with different solvents results in different products. Addition of quartz to the grinding mixture facilitates dechlorination efficiency, especially in the case of a high weight ratio of BP-Cl to CaO.",

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AU - Saito, Fumio

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AU - Tero-Kubota, Shozo

AU - Hatakeda, Kiyotaka

PY - 2001/12/15

Y1 - 2001/12/15

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AB - Grinding a mixture of 3-chlorobiphenyl (BP-Cl) and CaO with or without the addition of quartz was conducted in air by a planetary ball mill to investigate the mechanochemical dechlorination of BP-Cl. The dechlorinating reaction proceeds with an increase in grinding time, and over 99% of BP-Cl is decomposed at 360 min. Washing the ground sample with different solvents results in different products. Addition of quartz to the grinding mixture facilitates dechlorination efficiency, especially in the case of a high weight ratio of BP-Cl to CaO.

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Effects of quartz addition on the mechanochemical dechlorination of chlorobiphenyl by using CaO

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