Effects of Lewis acid on the sign of exchange interaction of photogenerated radical ion pairs

Shinji Sekiguchi; Kimio Akiyama; Shozo Tero-Kubota

doi:10.1039/a704366j

Effects of Lewis acid on the sign of exchange interaction of photogenerated radical ion pairs

Shinji Sekiguchi, Kimio Akiyama, Shozo Tero-Kubota

Division of Organic- and Biomaterials Research

Research output: Contribution to journal › Article › peer-review

5 Citations (Scopus)

Abstract

FTEPR study shows that the sign of the exchange interaction of the radical ion pair including the 4,4′-dimethoxybenzophenone radical anion and 1,4-diazabicyclo[2,2,2]-octane (DABCO) radical cation changes from positive to negative by addition of BF₃.

Original language	English
Pages (from-to)	1619-1620
Number of pages	2
Journal	Journal of the Chemical Society. Perkin Transactions 2
Issue number	9
DOIs	https://doi.org/10.1039/a704366j
Publication status	Published - 1997 Sep

ASJC Scopus subject areas

Chemistry(all)

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title = "Effects of Lewis acid on the sign of exchange interaction of photogenerated radical ion pairs",

abstract = "FTEPR study shows that the sign of the exchange interaction of the radical ion pair including the 4,4′-dimethoxybenzophenone radical anion and 1,4-diazabicyclo[2,2,2]-octane (DABCO) radical cation changes from positive to negative by addition of BF3.",

author = "Shinji Sekiguchi and Kimio Akiyama and Shozo Tero-Kubota",

year = "1997",

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doi = "10.1039/a704366j",

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journal = "Journal of the Chemical Society, Perkin Transactions 2",

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AU - Tero-Kubota, Shozo

PY - 1997/9

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AB - FTEPR study shows that the sign of the exchange interaction of the radical ion pair including the 4,4′-dimethoxybenzophenone radical anion and 1,4-diazabicyclo[2,2,2]-octane (DABCO) radical cation changes from positive to negative by addition of BF3.

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Effects of Lewis acid on the sign of exchange interaction of photogenerated radical ion pairs

Abstract

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