Effective control of two elimination processes from a hydridobis(silyl)iron(IV) complex

Takahiro Sato, Hiromi Tobita, Hiroshi Ogino

Research output: Contribution to journalArticlepeer-review

12 Citations (Scopus)

Abstract

A novel hydridobis(silyl)iron(IV) complex Cp*(CO)Fe(H)-(SiMe2O(2-C5H4N)}2 (1) (Cp*=η5-C5Me5) was synthesized in high yield. Two elimination processes from 1 were effectively controlled by the reaction conditions: HSiMe2O(Z-C5H4N) is eliminated on heating or UV-irradiation, whereas HO(2-C5H4N) is eliminated in the presence of Et3Al. The latter reaction was applied to a "silylene introduction" toward a silyl complex producing a silyl(silylene) complex.

Original languageEnglish
Pages (from-to)854-855
Number of pages2
JournalChemistry Letters
Issue number9
DOIs
Publication statusPublished - 2001 Jan 1

ASJC Scopus subject areas

  • Chemistry(all)

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