Effect of Cr addition on microstructure and oxidation resistance of a Ti5Si3-containing MoSiBTiC alloy

Tomotaka Hatakeyama; Nobuaki Sekido; Kyosuke Yoshimi

doi:10.1016/j.corsci.2019.108418

Effect of Cr addition on microstructure and oxidation resistance of a Ti₅Si₃-containing MoSiBTiC alloy

Tomotaka Hatakeyama, Nobuaki Sekido, Kyosuke Yoshimi

ENG - Materials Science

Research output: Contribution to journal › Article › peer-review

5 Citations (Scopus)

Abstract

The effect of Cr addition on the oxidation behaviour of multiphase Mo–28Ti–14Si–6C–6B (at. %) alloy composed of Mo solid solution, Mo₅SiB₂, Ti₅Si₃, and TiC phases was investigated. Replacement of 10 at. % Cr for Mo hardly changed the microstructure of the alloy and significantly enhanced its oxidation resistance at 800 °C. At 1100 °C, the Cr-added MoSiBTiC alloy showed less weight loss than the Cr-free base alloy. However, Cr addition had little effect on the substrate reduction, particularly for longer oxidation periods, due to the high volatility of Cr oxide at higher temperatures.

Original language	English
Article number	108418
Journal	Corrosion Science
Volume	166
DOIs	https://doi.org/10.1016/j.corsci.2019.108418
Publication status	Published - 2020 Apr 15

Keywords

A. Alloy
A. Intermetallics
B. Weight loss
C. High temperature corrosion
C. Oxidation

ASJC Scopus subject areas

Chemistry(all)
Chemical Engineering(all)
Materials Science(all)

Access to Document

10.1016/j.corsci.2019.108418

Cite this

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title = "Effect of Cr addition on microstructure and oxidation resistance of a Ti5Si3-containing MoSiBTiC alloy",

abstract = "The effect of Cr addition on the oxidation behaviour of multiphase Mo–28Ti–14Si–6C–6B (at. %) alloy composed of Mo solid solution, Mo5SiB2, Ti5Si3, and TiC phases was investigated. Replacement of 10 at. % Cr for Mo hardly changed the microstructure of the alloy and significantly enhanced its oxidation resistance at 800 °C. At 1100 °C, the Cr-added MoSiBTiC alloy showed less weight loss than the Cr-free base alloy. However, Cr addition had little effect on the substrate reduction, particularly for longer oxidation periods, due to the high volatility of Cr oxide at higher temperatures.",

keywords = "A. Alloy, A. Intermetallics, B. Weight loss, C. High temperature corrosion, C. Oxidation",

author = "Tomotaka Hatakeyama and Nobuaki Sekido and Kyosuke Yoshimi",

note = "Funding Information: This work was supported by the Advanced Low Carbon Technology Research and Development Program (ALCA) of the Japan Science and Technology Agency (JST) (No. JPMJAL1303 ). Funding Information: This work was supported by the Advanced Low Carbon Technology Research and Development Program (ALCA) of the Japan Science and Technology Agency (JST) (No. JPMJAL1303). Publisher Copyright: {\textcopyright} 2019 Elsevier Ltd",

year = "2020",

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doi = "10.1016/j.corsci.2019.108418",

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T1 - Effect of Cr addition on microstructure and oxidation resistance of a Ti5Si3-containing MoSiBTiC alloy

AU - Hatakeyama, Tomotaka

AU - Sekido, Nobuaki

AU - Yoshimi, Kyosuke

N1 - Funding Information: This work was supported by the Advanced Low Carbon Technology Research and Development Program (ALCA) of the Japan Science and Technology Agency (JST) (No. JPMJAL1303 ). Funding Information: This work was supported by the Advanced Low Carbon Technology Research and Development Program (ALCA) of the Japan Science and Technology Agency (JST) (No. JPMJAL1303). Publisher Copyright: © 2019 Elsevier Ltd

PY - 2020/4/15

Y1 - 2020/4/15

N2 - The effect of Cr addition on the oxidation behaviour of multiphase Mo–28Ti–14Si–6C–6B (at. %) alloy composed of Mo solid solution, Mo5SiB2, Ti5Si3, and TiC phases was investigated. Replacement of 10 at. % Cr for Mo hardly changed the microstructure of the alloy and significantly enhanced its oxidation resistance at 800 °C. At 1100 °C, the Cr-added MoSiBTiC alloy showed less weight loss than the Cr-free base alloy. However, Cr addition had little effect on the substrate reduction, particularly for longer oxidation periods, due to the high volatility of Cr oxide at higher temperatures.

AB - The effect of Cr addition on the oxidation behaviour of multiphase Mo–28Ti–14Si–6C–6B (at. %) alloy composed of Mo solid solution, Mo5SiB2, Ti5Si3, and TiC phases was investigated. Replacement of 10 at. % Cr for Mo hardly changed the microstructure of the alloy and significantly enhanced its oxidation resistance at 800 °C. At 1100 °C, the Cr-added MoSiBTiC alloy showed less weight loss than the Cr-free base alloy. However, Cr addition had little effect on the substrate reduction, particularly for longer oxidation periods, due to the high volatility of Cr oxide at higher temperatures.

KW - A. Alloy

KW - A. Intermetallics

KW - B. Weight loss

KW - C. High temperature corrosion

KW - C. Oxidation

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