Dynamic Chirality Control of (Xyl-)BIPHEP Ligands Leading to their Diastereomerically Pure Ru Complexes with a Chiral N-Substituted DPEN

Toshinobu Korenaga; Kohsuke Aikawa; Masahiro Terada; Susumu Kawauchi; Koichi Mikami

doi:10.1002/1615-4169(20010330)343:3<284::AID-ADSC284>3.0.CO;2-L

Dynamic Chirality Control of (Xyl-)BIPHEP Ligands Leading to their Diastereomerically Pure Ru Complexes with a Chiral N-Substituted DPEN

Toshinobu Korenaga, Kohsuke Aikawa, Masahiro Terada, Susumu Kawauchi, Koichi Mikami

Research output: Contribution to journal › Article › peer-review

49 Citations (Scopus)

Abstract

The metal complex of the chirally flexible biphenylphosphine (BIPHEP) exists as an equilibrium between the enantiomeric pairs due to the flexibility of BIPHEP. The dynamic chirality control of the BIPIIEP ligands in enantiomerically pure forms to give diastereomerically pure metal complexes with respect to their Ru(II) complexes by their molecular design with the introduction of a substituent in the chiral diamines rather than in the biphenylphosphine is described.

Original language	English
Pages (from-to)	284-288
Number of pages	5
Journal	Advanced Synthesis and Catalysis
Volume	343
Issue number	3
DOIs	https://doi.org/10.1002/1615-4169(20010330)343:3<284::AID-ADSC284>3.0.CO;2-L
Publication status	Published - 2001
Externally published	Yes

Keywords

BIPHEP
Diamine
Dynamic chirality control
Phosphine
Ruthenium

ASJC Scopus subject areas

Catalysis
Organic Chemistry

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10.1002/1615-4169(20010330)343:3<284::AID-ADSC284>3.0.CO;2-L

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title = "Dynamic Chirality Control of (Xyl-)BIPHEP Ligands Leading to their Diastereomerically Pure Ru Complexes with a Chiral N-Substituted DPEN",

abstract = "The metal complex of the chirally flexible biphenylphosphine (BIPHEP) exists as an equilibrium between the enantiomeric pairs due to the flexibility of BIPHEP. The dynamic chirality control of the BIPIIEP ligands in enantiomerically pure forms to give diastereomerically pure metal complexes with respect to their Ru(II) complexes by their molecular design with the introduction of a substituent in the chiral diamines rather than in the biphenylphosphine is described.",

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T1 - Dynamic Chirality Control of (Xyl-)BIPHEP Ligands Leading to their Diastereomerically Pure Ru Complexes with a Chiral N-Substituted DPEN

AU - Korenaga, Toshinobu

AU - Aikawa, Kohsuke

AU - Terada, Masahiro

AU - Kawauchi, Susumu

AU - Mikami, Koichi

PY - 2001

Y1 - 2001

N2 - The metal complex of the chirally flexible biphenylphosphine (BIPHEP) exists as an equilibrium between the enantiomeric pairs due to the flexibility of BIPHEP. The dynamic chirality control of the BIPIIEP ligands in enantiomerically pure forms to give diastereomerically pure metal complexes with respect to their Ru(II) complexes by their molecular design with the introduction of a substituent in the chiral diamines rather than in the biphenylphosphine is described.

AB - The metal complex of the chirally flexible biphenylphosphine (BIPHEP) exists as an equilibrium between the enantiomeric pairs due to the flexibility of BIPHEP. The dynamic chirality control of the BIPIIEP ligands in enantiomerically pure forms to give diastereomerically pure metal complexes with respect to their Ru(II) complexes by their molecular design with the introduction of a substituent in the chiral diamines rather than in the biphenylphosphine is described.

KW - BIPHEP

KW - Diamine

KW - Dynamic chirality control

KW - Phosphine

KW - Ruthenium

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DO - 10.1002/1615-4169(20010330)343:3<284::AID-ADSC284>3.0.CO;2-L

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AN - SCOPUS:0001192329

SN - 1615-4150

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JO - Advanced Synthesis and Catalysis

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Dynamic Chirality Control of (Xyl-)BIPHEP Ligands Leading to their Diastereomerically Pure Ru Complexes with a Chiral N-Substituted DPEN

Abstract

Keywords

ASJC Scopus subject areas

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