Dynamic behavior of pyrene fluorescence in highly oriented polymer LB films

Jun Matsui, Masaya Mitsuishi, Tokuji Miyashita

Research output: Contribution to journalArticlepeer-review

6 Citations (Scopus)

Abstract

The photophysical properties of the pyrene chromophore in poly(tert-pentylacrylamide-co-1-pyrenylmethyl acrylate) (p(tPA/PyMA)) Langmuir-Blodgett (LB) monolayer were studied. It is found that the emission property of the pyrene is drastically changed by capping with polymer LB films. When the pyrene monolayer was capped with poly(N-dodecylacrylamide) (p(DDA)) LB films, the emission intensity ratio of the excimer to the monomer (IEx/IMon) was increased with increasing temperature, whereas the IEx/IMon value was decreased with increasing temperature in the capping with poly(tert-pentylacrylamide) (p(tPA)) LB film. This interesting effect is discussed on the basis of the time-resolved emission spectroscopy.

Original languageEnglish
Pages (from-to)703-707
Number of pages5
JournalColloids and Surfaces A: Physicochemical and Engineering Aspects
Volume198-200
DOIs
Publication statusPublished - 2002 Feb 18

Keywords

  • Fluorescence
  • Poly(tert-pentylacrylamide)
  • Pyrene

ASJC Scopus subject areas

  • Surfaces and Interfaces
  • Physical and Theoretical Chemistry
  • Colloid and Surface Chemistry

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