Dynamic behavior of lithium-cation in a C60 fullerene cage elucidated by terahertz spectroscopy

Eunsang Kwon, Ken Ichirou Komatsu, Kazuhiko Kawachi, Yasuhiko Kasama, Tomoaki Endo

Research output: Contribution to journalArticlepeer-review

8 Citations (Scopus)

Abstract

This is the first report of the dynamic behavior of lithium-cation encapsulated in a C60 fullerene cage with terahertz (THz) spectroscopy. The THz spectroscopy of lithium-cation showed specific bands at 4.6 and 4.9 terahertz assigned to the two reciprocating vibrational modes, respectively, in the inside space of the fullerene cage.

Original languageEnglish
Pages (from-to)28-31
Number of pages4
JournalMolecular crystals and liquid crystals
Volume598
Issue number1
DOIs
Publication statusPublished - 2014 Jul 24

Keywords

  • DFT calculation
  • Endohedral metallofullerene
  • lithium-cation
  • terahertz spectroscopy

ASJC Scopus subject areas

  • Chemistry(all)
  • Materials Science(all)
  • Condensed Matter Physics

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