Dy(III) single-ion magnet showing extreme sensitivity to (De)hydration

Min Ren, Dawid Pinkowicz, Minyoung Yoon, Kimoon Kim, Li Min Zheng, Brian K. Breedlove, Masahiro Yamashita

Research output: Contribution to journalArticlepeer-review

55 Citations (Scopus)

Abstract

A new mononuclear dysprosium(III)-cucurbit[6]uril complex has been synthesized and characterized structurally and magnetically. It exhibits single-ion magnet (SIM) behavior with two slow magnetic relaxation processes, which are very sensitive to the solvation degree of the sample. Depending on the amount and type of the solvent in the structure, it is possible to switch the slow magnetic relaxation of this compound between the temperature-independent and temperature-dependent regimes.

Original languageEnglish
Pages (from-to)8342-8348
Number of pages7
JournalInorganic chemistry
Volume52
Issue number15
DOIs
Publication statusPublished - 2013 Aug 5

ASJC Scopus subject areas

  • Physical and Theoretical Chemistry
  • Inorganic Chemistry

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