Dual field effects in electrolyte-gated spinel ferrite: Electrostatic carrier doping and redox reactions

Takashi Ichimura, Kohei Fujiwara, Hidekazu Tanaka

Research output: Contribution to journalArticlepeer-review

13 Citations (Scopus)

Abstract

Controlling the electronic properties of functional oxide materials via external electric fields has attracted increasing attention as a key technology for next-generation electronics. For transition-metal oxides with metallic carrier densities, the electric-field effect with ionic liquid electrolytes has been widely used because of the enormous carrier doping capabilities. The gate-induced redox reactions revealed by recent investigations have, however, highlighted the complex nature of the electric-field effect. Here, we use the gate-induced conductance modulation of spinel Zn x Fe 3â ̂'x O 4 to demonstrate the dual contributions of volatile and non-volatile field effects arising from electronic carrier doping and redox reactions. These two contributions are found to change in opposite senses depending on the Zn content x; virtual electronic and chemical field effects are observed at appropriate Zn compositions. The tuning of field-effect characteristics via composition engineering should be extremely useful for fabricating high-performance oxide field-effect devices.

Original languageEnglish
Article number5818
JournalScientific reports
Volume4
DOIs
Publication statusPublished - 2014 Jul 24
Externally publishedYes

ASJC Scopus subject areas

  • General

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