Double core-hole states in SiX4 (X = F, Cl, Br, and CH3) molecules derived by photoelectron and KLL Auger spectroscopy

R. Püttner, T. Marchenko, R. Guillemin, L. Journel, G. Goldsztejn, J. P. Rueff, D. Céolin, D. W. Lindle, A. Lago, K. Ueda, O. Takahashi, M. N. Piancastelli, M. Simon

Research output: Contribution to journalConference articlepeer-review

Abstract

In recent years double core-hole states are intensively studied since their chemical shifts provide detailed information about initial-state and relaxation effects in a molecule. We derived the Si 1s-1, 2s-1, and 2p-1 binding energies as well as the Si 2s-2, 2s-1, 2p-1, and 2p-2 double-core hole binding energies of different SiX4 systems in order to derive the chemical shifts. Based on these results we created Wagner plots, which give insight in the initial state and the relaxation effects in the different molecules.

Original languageEnglish
Article number112057
JournalJournal of Physics: Conference Series
Volume635
Issue number11
DOIs
Publication statusPublished - 2015 Sep 7
Event29th International Conference on Photonic, Electronic and Atomic Collisions, ICPEAC 2015 - Toledo, Spain
Duration: 2015 Jul 222015 Jul 28

ASJC Scopus subject areas

  • Physics and Astronomy(all)

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