TY - JOUR
T1 - Distribution coefficients (K d) of stable iodine in estuarine and coastal regions, Japan, and their relationship to salinity and organic carbon in sediments
AU - Takata, Hyoe
AU - Zheng, Jian
AU - Tagami, Keiko
AU - Aono, Tatsuo
AU - Fujita, Kazuhiro
AU - Yamasaki, Shin Ichi
AU - Tsuchiya, Noriyoshi
AU - Uchida, Shigeo
N1 - Funding Information:
Acknowledgments We thank Mr. Shinichi Yamano, Mr. Masaki Matsui, Mss. Asada, Mss. Tamami Aragane (KANSO Technos Co., Ltd.), and Mr. Junichi Shirasaka (Tokyo Nuclear Service) for their technical support. We are also grateful for helpful comments on the manuscript from two anonymous reviewers. This work was partially supported by the Agency for Natural Resources and Energy, the Ministry of Economy, Trade and Industry (METI), Japan.
Copyright:
Copyright 2013 Elsevier B.V., All rights reserved.
PY - 2013/5
Y1 - 2013/5
N2 - The sediment-water distribution coefficient, K d, is one of the most important parameters in radionuclide assessment models. In this study, we determined K ds of stable iodine (I) in estuarine and coastal regions. We studied 16 estuarine and coastal regions of Japan and obtained I data on water and sediments. Data on salinity, pH, dissolved organic carbon and dissolved oxygen in water, and organic carbon (OC) in sediments were also obtained as estuarine variables. Determined K ds of I in the Sagami River estuary decreased along the salinity gradient (salinity range, 0.1-33.8), indicating that salinity is one of the important factors controlling the K d values; however, when the K d values were compared among all the estuaries, the difference between minimum and maximum K d values varied by about two orders of magnitude in a narrow salinity range of 30.0-34.4. A significant correlation between K d value and OC content in sediments was observed in all the stations with a salinity of ≥30 except for stations in the Ishikari and Onga River estuaries. The exceptions are probably due to different sources of the sediments, which are explained by the results of relatively low I/OC ratios in sediments in those two estuaries, compared to the other estuaries. Thus, OC in sediments as well as salinity may be responsible for the variation of K ds of I in the estuarine and coastal regions.
AB - The sediment-water distribution coefficient, K d, is one of the most important parameters in radionuclide assessment models. In this study, we determined K ds of stable iodine (I) in estuarine and coastal regions. We studied 16 estuarine and coastal regions of Japan and obtained I data on water and sediments. Data on salinity, pH, dissolved organic carbon and dissolved oxygen in water, and organic carbon (OC) in sediments were also obtained as estuarine variables. Determined K ds of I in the Sagami River estuary decreased along the salinity gradient (salinity range, 0.1-33.8), indicating that salinity is one of the important factors controlling the K d values; however, when the K d values were compared among all the estuaries, the difference between minimum and maximum K d values varied by about two orders of magnitude in a narrow salinity range of 30.0-34.4. A significant correlation between K d value and OC content in sediments was observed in all the stations with a salinity of ≥30 except for stations in the Ishikari and Onga River estuaries. The exceptions are probably due to different sources of the sediments, which are explained by the results of relatively low I/OC ratios in sediments in those two estuaries, compared to the other estuaries. Thus, OC in sediments as well as salinity may be responsible for the variation of K ds of I in the estuarine and coastal regions.
KW - Estuarine and coastal regions
KW - Organic carbon in sediments
KW - Salinity
KW - Stable iodine as an analog to radioactive iodine
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U2 - 10.1007/s10661-012-2816-5
DO - 10.1007/s10661-012-2816-5
M3 - Article
C2 - 22923376
AN - SCOPUS:84878356786
VL - 185
SP - 3645
EP - 3658
JO - Environmental Monitoring and Assessment
JF - Environmental Monitoring and Assessment
SN - 0167-6369
IS - 5
ER -