Dissolution characteristics and morphology of large-sized scorodite particles synthesized from Fe(II) and As(V) in aqueous solution

S. Fujieda, K. Shinoda, T. Inanaga, M. Abumiya, S. Suzuki

Research output: Contribution to journalArticle

4 Citations (Scopus)

Abstract

A novel process for preparing scorodite particles with a diameter of approximately 20 μm from Fe(II) and As(V) in aqueous solution has been developed by DOWA Metals and Mining. In the present study, the dissolution characteristics of iron and arsenic from the scorodite particles synthesized by this process have been investigated under different conditions. The results show that the concentration of arsenic dissolved from the particles in aqueous solution is very low, but it has a complicated dependence on the temperature and pH of the solution. Transmission electron microscopy (TEM) with an energy dispersive X-ray spectrometer (EDS) was used to analyze the morphology, structure, and composition of the scorodite particles. The results indicate that the scorodite particles exhibit a nearly octahedral shape with planes composed of almost (111) planes in the orthorhombic structure. The concentration of iron at the surface of the particles is higher than that of iron inside of the particles. This characteristic morphology, along with the minimal surface defects of the scorodite particles, is considered to be responsible for the low dissolution of arsenic from the particles in aqueous solution. Atmospheric temperature and solution conditions were also found to be important for the safe, long-term storage of arsenic using scorodite particles.

Original languageEnglish
Pages (from-to)451-458
Number of pages8
JournalHigh Temperature Materials and Processes
Volume31
Issue number4-5
DOIs
Publication statusPublished - 2012 Oct 1

Keywords

  • Arsenic
  • Dissolution
  • Scorodite
  • Solubility

ASJC Scopus subject areas

  • Materials Science(all)
  • Condensed Matter Physics
  • Mechanics of Materials
  • Physical and Theoretical Chemistry

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