Dissociation dynamics of core-excited BF3 probed by the photoelectron-photoion-photoion coincidence

M. Simon, P. Morin, P. Lablanquie, M. Lavollée, K. Ueda, N. Kosugi

Research output: Contribution to journalArticlepeer-review

49 Citations (Scopus)

Abstract

The present photoelectron-photoion-photoion coincidence measurement indicates that the dynamics of ion-pair production following the discrete resonance excitation B 1s → 2a″2 are completely different from those following the B 1s ionization and the direct double photoionization. The difference is attributed to deformation of the core-excited 2a″2 state with the help of ab initio SCF calculation.

Original languageEnglish
Pages (from-to)42-46
Number of pages5
JournalChemical Physics Letters
Volume238
Issue number1-3
DOIs
Publication statusPublished - 1995 May 26

ASJC Scopus subject areas

  • Physics and Astronomy(all)
  • Physical and Theoretical Chemistry

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