Dissociation dynamics of core-excited BF3 probed by the photoelectron-photoion-photoion coincidence

M. Simon; P. Morin; P. Lablanquie; M. Lavollée; K. Ueda; N. Kosugi

doi:10.1016/0009-2614(95)00382-7

Dissociation dynamics of core-excited BF₃ probed by the photoelectron-photoion-photoion coincidence

M. Simon, P. Morin, P. Lablanquie, M. Lavollée, K. Ueda, N. Kosugi

Division of Measurements

Research output: Contribution to journal › Article › peer-review

49 Citations (Scopus)

Abstract

The present photoelectron-photoion-photoion coincidence measurement indicates that the dynamics of ion-pair production following the discrete resonance excitation B 1s → 2a″₂ are completely different from those following the B 1s ionization and the direct double photoionization. The difference is attributed to deformation of the core-excited 2a″₂ state with the help of ab initio SCF calculation.

Original language	English
Pages (from-to)	42-46
Number of pages	5
Journal	Chemical Physics Letters
Volume	238
Issue number	1-3
DOIs	https://doi.org/10.1016/0009-2614(95)00382-7
Publication status	Published - 1995 May 26

ASJC Scopus subject areas

Physics and Astronomy(all)
Physical and Theoretical Chemistry

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10.1016/0009-2614(95)00382-7

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abstract = "The present photoelectron-photoion-photoion coincidence measurement indicates that the dynamics of ion-pair production following the discrete resonance excitation B 1s → 2a″2 are completely different from those following the B 1s ionization and the direct double photoionization. The difference is attributed to deformation of the core-excited 2a″2 state with the help of ab initio SCF calculation.",

author = "M. Simon and P. Morin and P. Lablanquie and M. Lavoll{\'e}e and K. Ueda and N. Kosugi",

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T1 - Dissociation dynamics of core-excited BF3 probed by the photoelectron-photoion-photoion coincidence

AU - Simon, M.

AU - Morin, P.

AU - Lablanquie, P.

AU - Lavollée, M.

AU - Ueda, K.

AU - Kosugi, N.

PY - 1995/5/26

Y1 - 1995/5/26

N2 - The present photoelectron-photoion-photoion coincidence measurement indicates that the dynamics of ion-pair production following the discrete resonance excitation B 1s → 2a″2 are completely different from those following the B 1s ionization and the direct double photoionization. The difference is attributed to deformation of the core-excited 2a″2 state with the help of ab initio SCF calculation.

AB - The present photoelectron-photoion-photoion coincidence measurement indicates that the dynamics of ion-pair production following the discrete resonance excitation B 1s → 2a″2 are completely different from those following the B 1s ionization and the direct double photoionization. The difference is attributed to deformation of the core-excited 2a″2 state with the help of ab initio SCF calculation.

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JF - Chemical Physics Letters

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Dissociation dynamics of core-excited BF₃ probed by the photoelectron-photoion-photoion coincidence

Abstract

ASJC Scopus subject areas

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