Discovery of stable icosahedral quasicrystals: Progress in understanding structure and properties

An Pang Tsai

    Research output: Contribution to journalArticlepeer-review

    70 Citations (Scopus)

    Abstract

    The geometrical concept and structural framework of quasicrystals (QCs) were established shortly after the discovery of QCs. Specifically, the static and dynamic properties of the atoms and the electronic structures of quasiperiodic lattices were theoretically developed. Experimental studies lagged behind theoretical progress due to the lack of suitable samples. This situation changed with the discovery of several highly ordered stable QCs. Studies of these new QCs have provided new insights into the structure and properties of QCs. This article chronologically reviews the discoveries of various stable icosahedral QCs and subsequent studies that determined their structures, properties, and stabilization mechanisms.

    Original languageEnglish
    Pages (from-to)5352-5365
    Number of pages14
    JournalChemical Society Reviews
    Volume42
    Issue number12
    DOIs
    Publication statusPublished - 2013 May 28

    ASJC Scopus subject areas

    • Chemistry(all)

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